Properties of Cobalt- and Nickel-Doped Zif-8 Framework Materials and Their Application in Heavy-Metal Removal from Wastewater

Overview

Journal Nanomaterials (Basel)

Date 2020 Aug 23

PMID 32825379

Citations 9

Authors

Bowen Shen

Bixuan Wang

Liying Zhu

Ling Jiang

Affiliations

Soon will be listed here.

Abstract

Heterometallic zeolite imidazole framework materials (ZIF) exhibit highly attractive properties and have drawn increased attention. In this study, a petal-like zinc based ZIF-8 crystal and materials doped with cobalt and nickel ions were efficiently prepared in an aqueous solution at room temperature. It was observed that doped cobalt and nickel had obviously different effects on the morphology of ZIF-8. Cobalt ions were beneficial for the formation of ZIF-8, while addition of nickel ions tended to destroy the original configuration. Then we compared the absorption ability for metal ions between petal-like ZIF-8 and its doped derivatives with anion dichromate ions (CrO) and cation copper ions (Cu) as the absorbates. Results indicated that saturated adsorption capacities of Co@ZIF-8 and Ni@ZIF-8 for CrO reach 43.00 and 51.60 mg/g, while they are 1191.67 and 1066.67 mg/g for Cu, respectively, which are much higher than the original ZIF-8 materials. Furthermore, both the heterometallic ZIF-8 materials show fast adsorption kinetics to reach adsorption equilibrium. Therefore, petal-like ZIF-8 with doped ions can be produced through a facile method and can be an excellent candidate for further applications in heavy-metal treatment.

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References

Jiang H, Liu B, Akita T, Haruta M, Sakurai H, Xu Q . Au@ZIF-8: CO oxidation over gold nanoparticles deposited to metal-organic framework. J Am Chem Soc. 2009; 131(32):11302-3. DOI: 10.1021/ja9047653. View

Gupta K, Ghosh U . Arsenic removal using hydrous nanostructure iron(III)-titanium(IV) binary mixed oxide from aqueous solution. J Hazard Mater. 2008; 161(2-3):884-92. DOI: 10.1016/j.jhazmat.2008.04.034. View

Saliba D, Ammar M, Rammal M, Al-Ghoul M, Hmadeh M . Crystal Growth of ZIF-8, ZIF-67, and Their Mixed-Metal Derivatives. J Am Chem Soc. 2018; 140(5):1812-1823. DOI: 10.1021/jacs.7b11589. View

Lu G, Li S, Guo Z, Farha O, Hauser B, Qi X . Imparting functionality to a metal-organic framework material by controlled nanoparticle encapsulation. Nat Chem. 2012; 4(4):310-6. DOI: 10.1038/nchem.1272. View

Xu X, Ji D, Zhang Y, Gao X, Xu P, Li X . Detection of Phenylketonuria Markers Using a ZIF-67 Encapsulated PtPd Alloy Nanoparticle (PtPd@ZIF-67)-Based Disposable Electrochemical Microsensor. ACS Appl Mater Interfaces. 2019; 11(23):20734-20742. DOI: 10.1021/acsami.9b05431. View

Wang H, Yuan X, Wu Y, Zeng G, Chen X, Leng L . Facile synthesis of amino-functionalized titanium metal-organic frameworks and their superior visible-light photocatalytic activity for Cr(VI) reduction. J Hazard Mater. 2015; 286:187-94. DOI: 10.1016/j.jhazmat.2014.11.039. View

Perez-Pellitero J, Amrouche H, Siperstein F, Pirngruber G, Nieto-Draghi C, Chaplais G . Adsorption of CO(2), CH(4), and N(2) on zeolitic imidazolate frameworks: experiments and simulations. Chemistry. 2009; 16(5):1560-71. DOI: 10.1002/chem.200902144. View

Navarro Poupard M, Polo E, Taboada P, Arenas-Vivo A, Horcajada P, Pelaz B . Aqueous Synthesis of Copper(II)-Imidazolate Nanoparticles. Inorg Chem. 2018; 57(19):12056-12065. DOI: 10.1021/acs.inorgchem.8b01612. View

Wu X, Yang C, Ge J, Liu Z . Polydopamine tethered enzyme/metal-organic framework composites with high stability and reusability. Nanoscale. 2015; 7(45):18883-6. DOI: 10.1039/c5nr05190h. View

10.

Liang K, Richardson J, Doonan C, Mulet X, Ju Y, Cui J . An Enzyme-Coated Metal-Organic Framework Shell for Synthetically Adaptive Cell Survival. Angew Chem Int Ed Engl. 2017; 56(29):8510-8515. DOI: 10.1002/anie.201704120. View

11.

Huang X, Lin Y, Zhang J, Chen X . Ligand-directed strategy for zeolite-type metal-organic frameworks: zinc(II) imidazolates with unusual zeolitic topologies. Angew Chem Int Ed Engl. 2006; 45(10):1557-9. DOI: 10.1002/anie.200503778. View

12.

Ricco R, Liang W, Li S, Gassensmith J, Caruso F, Doonan C . Metal-Organic Frameworks for Cell and Virus Biology: A Perspective. ACS Nano. 2018; 12(1):13-23. DOI: 10.1021/acsnano.7b08056. View

13.

Shahrak M, Ghahramaninezhad M, Eydifarash M . Zeolitic imidazolate framework-8 for efficient adsorption and removal of Cr(VI) ions from aqueous solution. Environ Sci Pollut Res Int. 2017; 24(10):9624-9634. DOI: 10.1007/s11356-017-8577-5. View

14.

Zhang T, Song Y, Xing Y, Gu Y, Yan X, Liu H . The synergistic effect of Au-COF nanosheets and artificial peroxidase Au@ZIF-8(NiPd) rhombic dodecahedra for signal amplification for biomarker detection. Nanoscale. 2019; 11(42):20221-20227. DOI: 10.1039/c9nr07190c. View

15.

Pan Y, Liu Y, Zeng G, Zhao L, Lai Z . Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system. Chem Commun (Camb). 2011; 47(7):2071-3. DOI: 10.1039/c0cc05002d. View

16.

Chizallet C, Lazare S, Bazer-Bachi D, Bonnier F, Lecocq V, Soyer E . Catalysis of transesterification by a nonfunctionalized metal-organic framework: acido-basicity at the external surface of ZIF-8 probed by FTIR and ab initio calculations. J Am Chem Soc. 2010; 132(35):12365-77. DOI: 10.1021/ja103365s. View

17.

Gucuyener C, Van den Bergh J, Gascon J, Kapteijn F . Ethane/ethene separation turned on its head: selective ethane adsorption on the metal-organic framework ZIF-7 through a gate-opening mechanism. J Am Chem Soc. 2010; 132(50):17704-6. DOI: 10.1021/ja1089765. View

18.

Wang X, Liu J, Leong S, Lin X, Wei J, Kong B . Rapid Construction of ZnO@ZIF-8 Heterostructures with Size-Selective Photocatalysis Properties. ACS Appl Mater Interfaces. 2016; 8(14):9080-7. DOI: 10.1021/acsami.6b00028. View

19.

Li N, Zhou L, Jin X, Owens G, Chen Z . Simultaneous removal of tetracycline and oxytetracycline antibiotics from wastewater using a ZIF-8 metal organic-framework. J Hazard Mater. 2018; 366:563-572. DOI: 10.1016/j.jhazmat.2018.12.047. View

20.

Van den Bergh J, Gucuyener C, Pidko E, Hensen E, Gascon J, Kapteijn F . Understanding the anomalous alkane selectivity of ZIF-7 in the separation of light alkane/alkene mixtures. Chemistry. 2011; 17(32):8832-40. DOI: 10.1002/chem.201100958. View