Reversible Switching Between Nonporous and Porous Phases of a New SIFSIX Coordination Network Induced by a Flexible Linker Ligand

Overview

Journal J Am Chem Soc

Publisher American Chemical Society

Specialty Chemistry

Date 2020 Mar 29

PMID 32216372

Citations 9

Authors

Bai-Qiao Song

Qing-Yuan Yang

Shi-Qiang Wang

Matthias Vandichel

Amrit Kumar

Clare Crowley

Naveen Kumar

Cheng-Hua Deng

Victoria GasconPerez

Matteo Lusi

Hui Wu

Wei Zhou

Michael J Zaworotko

Affiliations

Soon will be listed here.

Abstract

Closed-to-open structural transformations in flexible coordination networks are of potential utility in gas storage and separation. Herein, we report the first example of a flexible SiF-pillared square grid material, [Cu(SiF)(L)] (L = 1,4-bis(1-imidazolyl)benzene), . exhibits reversible switching between nonporous () and several porous (, , , and ) phases triggered by exposure to N, CO, or HO. In addition, heating to 433 K resulted in irreversible transformation to a closed polymorph, . Single-crystal X-ray diffraction studies revealed that the phase transformations are enabled by rotation and geometrical contortion of L. Density functional theory calculations indicated that L exhibits a low barrier to rotation (as low as 8 kJmol) and a rather flat energy surface. In situ neutron powder diffraction studies provided further insight into these sorbate-induced phase changes. combines stability in water for over a year, high CO uptake (ca. 216 cm/g at 195 K), and good thermal stability.

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References

Shekhah O, Belmabkhout Y, Chen Z, Guillerm V, Cairns A, Adil K . Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture. Nat Commun. 2014; 5:4228. PMC: 4083436. DOI: 10.1038/ncomms5228. View

Adil K, Belmabkhout Y, Pillai R, Cadiau A, Bhatt P, Assen A . Gas/vapour separation using ultra-microporous metal-organic frameworks: insights into the structure/separation relationship. Chem Soc Rev. 2017; 46(11):3402-3430. DOI: 10.1039/c7cs00153c. View

Seo J, Matsuda R, Sakamoto H, Bonneau C, Kitagawa S . A pillared-layer coordination polymer with a rotatable pillar acting as a molecular gate for guest molecules. J Am Chem Soc. 2009; 131(35):12792-800. DOI: 10.1021/ja904363b. View

Engel E, Jouaiti A, Bezuidenhout C, Hosseini M, Barbour L . Activation-Dependent Breathing in a Flexible Metal-Organic Framework and the Effects of Repeated Sorption/Desorption Cycling. Angew Chem Int Ed Engl. 2017; 56(30):8874-8878. DOI: 10.1002/anie.201704044. View

Mason J, Oktawiec J, Taylor M, Hudson M, Rodriguez J, Bachman J . Methane storage in flexible metal-organic frameworks with intrinsic thermal management. Nature. 2015; 527(7578):357-61. DOI: 10.1038/nature15732. View

Furukawa H, Cordova K, OKeeffe M, Yaghi O . The chemistry and applications of metal-organic frameworks. Science. 2013; 341(6149):1230444. DOI: 10.1126/science.1230444. View

Deria P, Gomez-Gualdron D, Bury W, Schaef H, Wang T, Thallapally P . Ultraporous, Water Stable, and Breathing Zirconium-Based Metal-Organic Frameworks with ftw Topology. J Am Chem Soc. 2015; 137(40):13183-90. DOI: 10.1021/jacs.5b08860. View

Zhang Y, Zhang X, Lyu J, Otake K, Wang X, Redfern L . A Flexible Metal-Organic Framework with 4-Connected Zr Nodes. J Am Chem Soc. 2018; 140(36):11179-11183. DOI: 10.1021/jacs.8b06789. View

Kitagawa S, Kitaura R, Noro S . Functional porous coordination polymers. Angew Chem Int Ed Engl. 2004; 43(18):2334-75. DOI: 10.1002/anie.200300610. View

10.

Chen L, Mowat J, Fairen-Jimenez D, Morrison C, Thompson S, Wright P . Elucidating the breathing of the metal-organic framework MIL-53(Sc) with ab initio molecular dynamics simulations and in situ X-ray powder diffraction experiments. J Am Chem Soc. 2013; 135(42):15763-73. DOI: 10.1021/ja403453g. View

11.

Katsoulidis A, Antypov D, Whitehead G, Carrington E, Adams D, Berry N . Chemical control of structure and guest uptake by a conformationally mobile porous material. Nature. 2019; 565(7738):213-217. DOI: 10.1038/s41586-018-0820-9. View

12.

Nugent P, Belmabkhout Y, Burd S, Cairns A, Luebke R, Forrest K . Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation. Nature. 2013; 495(7439):80-4. DOI: 10.1038/nature11893. View

13.

Liu D, Liu T, Chen Y, Zou L, Feng D, Wang K . A Reversible Crystallinity-Preserving Phase Transition in Metal-Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications. J Am Chem Soc. 2015; 137(24):7740-6. DOI: 10.1021/jacs.5b02999. View

14.

Gucuyener C, Van den Bergh J, Gascon J, Kapteijn F . Ethane/ethene separation turned on its head: selective ethane adsorption on the metal-organic framework ZIF-7 through a gate-opening mechanism. J Am Chem Soc. 2010; 132(50):17704-6. DOI: 10.1021/ja1089765. View

15.

Wang S, Mukherjee S, Patyk-Kazmierczak E, Darwish S, Bajpai A, Yang Q . Highly Selective, High-Capacity Separation of o-Xylene from C Aromatics by a Switching Adsorbent Layered Material. Angew Chem Int Ed Engl. 2019; 58(20):6630-6634. DOI: 10.1002/anie.201901198. View

16.

Elsaidi S, Mohamed M, Simon C, Braun E, Pham T, Forrest K . Effect of ring rotation upon gas adsorption in SIFSIX-3-M (M = Fe, Ni) pillared square grid networks. Chem Sci. 2017; 8(3):2373-2380. PMC: 5364996. DOI: 10.1039/c6sc05012c. View

17.

Zhou D, Chen P, Wang C, Wang S, Du Y, Yan H . Intermediate-sized molecular sieving of styrene from larger and smaller analogues. Nat Mater. 2019; 18(9):994-998. DOI: 10.1038/s41563-019-0427-z. View

18.

Schneemann A, Bon V, Schwedler I, Senkovska I, Kaskel S, Fischer R . Flexible metal-organic frameworks. Chem Soc Rev. 2014; 43(16):6062-96. DOI: 10.1039/c4cs00101j. View

19.

Serre C, Mellot-Draznieks C, Surble S, Audebrand N, Filinchuk Y, Ferey G . Role of solvent-host interactions that lead to very large swelling of hybrid frameworks. Science. 2007; 315(5820):1828-31. DOI: 10.1126/science.1137975. View

20.

Rabone J, Yue Y, Chong S, Stylianou K, Bacsa J, Bradshaw D . An adaptable peptide-based porous material. Science. 2010; 329(5995):1053-7. DOI: 10.1126/science.1190672. View