Spin Transition in a Ferrous Chloride Complex Supported by a Pentapyridine Ligand
Overview
Overview
Journal
Chem Commun (Camb)
Publisher
Royal Society of Chemistry
Specialty
Chemistry
Date
2020 Feb 15
PMID
32057045
Citations
1
Authors
Authors
Affiliations
Affiliations
Soon will be listed here.
Abstract
Ferrous chloride complexes [FeLCl] commonly attain a high-spin state independently of the supporting ligand(s) and temperature. Herein, we present the first report of a complete spin crossover with T = 80 K in [Fe(Py5OH)Cl] (Py5OH = pyridine-2,6-diylbis[di(pyridin-2-yl)methanol]). Both spin forms of the complex are analyzed by X-ray spectroscopy and DFT calculations.
Citing Articles
Water Oxidation by Pentapyridyl Base Metal Complexes? A Case Study.
Boniolo M, Hossain M, Chernev P, Suremann N, Heizmann P, Lyvik A Inorg Chem. 2022; 61(24):9104-9118.
PMID: 35658429 PMC: 9214691. DOI: 10.1021/acs.inorgchem.2c00631.