Bismuthanylstibanes

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2020 Feb 7

PMID 32026911

Citations 6

Authors

Katherine M Marczenko

Saurabh S Chitnis

Affiliations

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Abstract

Thermally-robust bismuthanylstibanes are prepared in a one-step, high yield reaction, providing the first examples of neutral Bi-Sb σ-bonds in the solid state. DFT calculations indicate that the bis(silylamino)naphthalene scaffold is well-suited for supporting otherwise labile bonds. The reaction chemistry of the Bi-Sb bond is debuted by showing fission using NHBH and insertion of a sulfur atom, the latter providing the first example of a Bi-S-Sb motif.

Citing Articles

Synthesis of bismuthanyl-substituted monomeric triel hydrides.

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Heavy Chains: Synthesis, Reactivity and Decomposition of Interpnictogen Chains with Terminal Diaryl Bismuth Fragments.

Dunaj T, von Hanisch C Chemistry. 2022; 28(69):e202202932.

PMID: 36409832 PMC: 10099782. DOI: 10.1002/chem.202202932.

Structural diversity of mixed polypnictogen complexes: dicationic EE' (E ≠ E' = P, As, Sb, Bi) chains, cycles and cages stabilized by transition metals.

Dutsch L, Riesinger C, Balazs G, Seidl M, Scheer M Chem Sci. 2021; 12(43):14531-14539.

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Synthesis of Tetrahedranes Containing the Unique Bridging Hetero-Dipnictogen Ligand EE' (E ≠ E'=P, As, Sb, Bi).

Dutsch L, Riesinger C, Balazs G, Scheer M Chemistry. 2021; 27(34):8804-8810.

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Carbodicarbene Bismaalkene Cations: Unravelling the Complexities of Carbene versus Carbone in Heavy Pnictogen Chemistry.

Walley J, Warring L, Wang G, Dickie D, Pan S, Frenking G Angew Chem Int Ed Engl. 2020; 60(12):6682-6690.

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