Syntheses, Structures, and Characteristics of Three Metal Complexes Constructed Using Hexacarboxylic Acid

Overview

Journal Molecules

Publisher MDPI

Specialty Biology

Date 2019 Dec 11

PMID 31817115

Authors

Lingshu Meng

Lun Zhao

Guanlin Guo

Xin Liu

Zhijun Liang

Jian Xiu

Xu Zhou

Affiliations

Soon will be listed here.

Abstract

In this study, three new 3D coordination polymers (CPs), {[Cd(L)(HO)]·HO} (), {[Cu(L)(bimb)]·5HO·DMF} (), and {[Mn(HL)(bibp)(HO)]·3HO} () (= 1,3-bis(imidazol-1-yl)benzene, = 1,4-bis((4-imidazol-1-yl)benzyl)piperazine), were prepared under solvothermal or hydrothermal conditions based on a hexadentate ligand (1,3,5-triazine-2,4,6-triamine hexa-acetic acid (HL)). Structural elucidations were carried out by IR spectra along with single-crystal X-ray diffraction analysis, while thermogravimetric analysis (TGA) (dynamic and isothermal) and XRD techniques were used for property evaluations of the polymers. Furthermore, the fluorescence properties and detection of the Fe ions in were tested at room temperature, and the electrochemical behavior of is also stated in this article.

References

Hyman L, Franz K . Probing oxidative stress: Small molecule fluorescent sensors of metal ions, reactive oxygen species, and thiols. Coord Chem Rev. 2013; 256(19-20):2333-2356. PMC: 3579673. DOI: 10.1016/j.ccr.2012.03.009. View

Thomas 3rd S, Joly G, Swager T . Chemical sensors based on amplifying fluorescent conjugated polymers. Chem Rev. 2007; 107(4):1339-86. DOI: 10.1021/cr0501339. View

Chen X, Liu G . Double-stranded helices and molecular zippers assembled from single-stranded coordination polymers directed by supramolecular interactions. Chemistry. 2003; 8(20):4811-7. DOI: 10.1002/1521-3765(20021018)8:20<4811::AID-CHEM4811>3.0.CO;2-R. View

Li M, Li D, OKeeffe M, Yaghi O . Topological analysis of metal-organic frameworks with polytopic linkers and/or multiple building units and the minimal transitivity principle. Chem Rev. 2013; 114(2):1343-70. DOI: 10.1021/cr400392k. View

Zhao X, Tian D, Gao Q, Sun H, Xu J, Bu X . A chiral lanthanide metal-organic framework for selective sensing of Fe(iii) ions. Dalton Trans. 2015; 45(3):1040-6. DOI: 10.1039/c5dt03283k. View

Gole B, Sanyal U, Banerjee R, Mukherjee P . High Loading of Pd Nanoparticles by Interior Functionalization of MOFs for Heterogeneous Catalysis. Inorg Chem. 2016; 55(5):2345-54. DOI: 10.1021/acs.inorgchem.5b02739. View

Hua J, Zhao Y, Kang Y, Lu Y, Sun W . Solvent-dependent zinc(II) coordination polymers with mixed ligands: selective sorption and fluorescence sensing. Dalton Trans. 2015; 44(25):11524-32. DOI: 10.1039/c5dt01386k. View

Zhou H, Kitagawa S . Metal-organic frameworks (MOFs). Chem Soc Rev. 2014; 43(16):5415-8. DOI: 10.1039/c4cs90059f. View

Jiang J, Yaghi O . Brønsted acidity in metal-organic frameworks. Chem Rev. 2015; 115(14):6966-97. DOI: 10.1021/acs.chemrev.5b00221. View

10.

Song J, Gao X, Wang Z, Li C, Xu Q, Bai F . Multifunctional uranyl hybrid materials: structural diversities as a function of pH, luminescence with potential nitrobenzene sensing, and photoelectric behavior as p-type semiconductors. Inorg Chem. 2015; 54(18):9046-59. DOI: 10.1021/acs.inorgchem.5b01364. View

11.

Hill R, Long D, Champness N, Hubberstey P, Schroder M . New approaches to the analysis of high connectivity materials: design frameworks based upon 4(4)- and 6(3)-subnet tectons. Acc Chem Res. 2005; 38(4):335-48. DOI: 10.1021/ar040174b. View

12.

Han S, Song W, Zhao J, Yang Q, Liu S, Li Y . Synthesis and ferrimagnetic properties of an unprecedented polynuclear cobalt complex composed of [Co24] macrocycles. Chem Commun (Camb). 2012; 49(9):871-3. DOI: 10.1039/c2cc37593a. View

13.

Zhang S, Yang J, Wu H, Liu Y, Ma J . Systematic Investigation of High-Sensitivity Luminescent Sensing for Polyoxometalates and Iron(III) by MOFs Assembled with a New Resorcin[4]arene-Functionalized Tetracarboxylate. Chemistry. 2015; 21(44):15806-19. DOI: 10.1002/chem.201501976. View

14.

Barba-Bon A, Costero A, Gil S, Parra M, Soto J, Martinez-Manez R . A new selective fluorogenic probe for trivalent cations. Chem Commun (Camb). 2012; 48(24):3000-2. DOI: 10.1039/c2cc17184h. View

15.

Feng X, Feng Y, Guo N, Sun Y, Zhang T, Ma L . Series d-f Heteronuclear Metal-Organic Frameworks: Color Tunability and Luminescent Probe with Switchable Properties. Inorg Chem. 2017; 56(3):1713-1721. DOI: 10.1021/acs.inorgchem.6b02851. View

16.

Wen G, Wu Y, Dong W, Zhao J, Li D, Zhang J . An Ultrastable Europium(III)-Organic Framework with the Capacity of Discriminating Fe/Fe Ions in Various Solutions. Inorg Chem. 2016; 55(20):10114-10117. DOI: 10.1021/acs.inorgchem.6b01876. View

17.

Akhbari K, Morsali A . Modulating methane storage in anionic nano-porous MOF materials via post-synthetic cation exchange process. Dalton Trans. 2013; 42(14):4786-9. DOI: 10.1039/c3dt32846e. View

18.

Liang Y, Yang G, Liu B, Yan Y, Xi Z, Wang Y . Four super water-stable lanthanide-organic frameworks with active uncoordinated carboxylic and pyridyl groups for selective luminescence sensing of Fe(3.). Dalton Trans. 2015; 44(29):13325-30. DOI: 10.1039/c5dt01421b. View

19.

Sheldrick G . SHELXT - integrated space-group and crystal-structure determination. Acta Crystallogr A Found Adv. 2014; 71(Pt 1):3-8. PMC: 4283466. DOI: 10.1107/S2053273314026370. View

20.

Hu F, Shi Y, Chen H, Lang J . A Zn(II) coordination polymer and its photocycloaddition product: syntheses, structures, selective luminescence sensing of iron(III) ions and selective absorption of dyes. Dalton Trans. 2015; 44(43):18795-803. DOI: 10.1039/c5dt03094c. View