Magnetic Solid-Phase Extraction of Pyrethroid Pesticides from Environmental Water Samples Using Deep Eutectic Solvent-type Surfactant Modified Magnetic Zeolitic Imidazolate Framework-8

Overview

Journal Molecules

Publisher MDPI

Specialty Biology

Date 2019 Nov 10

PMID 31703405

Citations 8

Authors

Huifang Liu

Lihua Jiang

Meng Lu

Guangyang Liu

Tengfei Li

Xiaomin Xu

Lingyun Li

Huan Lin

Jun Lv

Xiaodong Huang

Donghui Xu

Affiliations

Soon will be listed here.

Abstract

A simple, sensitive and effective magnetic solid-phase extraction (MSPE) technique was developed for the extraction of pyrethroid pesticides from environmental water samples, followed by gas chromatography tandem triple quadrupole mass spectrometry determination. An adsorbent of magnetic zeolitic imidazolate framework-8@deep eutectic solvent (M-ZIF-8@DES) was prepared using deep eutectic solvent coated on the surface of M-ZIF-8. The features of M-ZIF-8@DES were confirmed by material characterizations, and the results indicated that M-ZIF-8@DES has a good magnetism (61.3 emu g), a decent surface area (96.83 m g) and pore volume (0.292 mL g). Single factor experiments were carried out to investigate the effect of different conditions on the performance of MSPE. Under the optimal conditions, the developed method performs good linearity (R ≥ 0.9916) in the concentration range of 1-500 μg L. The limits of detection were in the range of 0.05-0.21 μg L (signal/noise = 3/1). The intraday relative standard deviation (RSD) and interday RSD were less than 9.40%. Finally, the proposed technique was applied for the determination of pyrethroid pesticides in environmental water samples. This work shows the potential of DES-modified metal-organic frameworks for different sample pretreatment techniques.

Citing Articles

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