Train of Single Molecule-Gears
Overview
Affiliations
Two molecule-gears, 1.2 nm in diameter with six teeth, are mounted each on a single copper adatom separated exactly by 1.9 nm on a lead surface using a low-temperature scanning tunneling microscope (LT-STM). A functioning train of two molecule-gears is constructed complete with a molecule-handle. Not mounted on a Cu adatom axle, this ancillary molecule-gear is mechanically engaged with the first molecule-gear of the train to stabilize its step-by-step rotation. Centered on its Cu adatom axle, the rotation of the first gear of the train step by step rotates the second similar to a train of macroscopic gears. From the handle to the first and to this second molecule-gear, the exact positioning of the two Cu adatom axles on the lead surface ensures that the molecular teeth-to-teeth mechanics is fully reversible.
Mechanically Interlocked Molecular Rotors on Pb(100).
Li C, Lu Y, Li R, Wang L, Weismann A, Berndt R Nano Lett. 2025; 25(4):1504-1511.
PMID: 39806267 PMC: 11783589. DOI: 10.1021/acs.nanolett.4c05409.
2D Materials Nanoarchitectonics for 3D Structures/Functions.
Ariga K Materials (Basel). 2024; 17(4).
PMID: 38399187 PMC: 10890396. DOI: 10.3390/ma17040936.
Materials Nanoarchitectonics at Dynamic Interfaces: Structure Formation and Functional Manipulation.
Ariga K Materials (Basel). 2024; 17(1).
PMID: 38204123 PMC: 10780059. DOI: 10.3390/ma17010271.
Molecular Machines and Microrobots: Nanoarchitectonics Developments and On-Water Performances.
Ariga K Micromachines (Basel). 2023; 14(1).
PMID: 36677086 PMC: 9860627. DOI: 10.3390/mi14010025.
Molecule-to-Material-to-Bio Nanoarchitectonics with Biomedical Fullerene Nanoparticles.
Shen X, Song J, Kawakami K, Ariga K Materials (Basel). 2022; 15(15).
PMID: 35955337 PMC: 9369991. DOI: 10.3390/ma15155404.