Black/red Phosphorus Quantum Dots for Photocatalytic Water Splitting: from a Type I Heterostructure to a Z-scheme System
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By virtue of the quantum confinement effect, the junction between black phosphorus and red phosphorus changes from a type I heterostructure for bulk materials to a Z-scheme system for quantum dots. The Z-scheme system of black/red phosphorus quantum dots (BP/RP-QD) achieves H evolution from water splitting in the absence of sacrificial agents.
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