Mechanistic Study on Allylic Arylation in Water with Linear Polystyrene-Stabilized Pd and PdO Nanoparticles

Overview

Journal ACS Omega

Publisher American Chemical Society

Specialty Chemistry

Date 2019 Oct 2

PMID 31572880

Citations 2

Authors

Atsushi Ohtaka

Misa Kawase

Akira Usami

Shiho Fukui

Mana Yamashita

Kazuki Yamaguchi

Akira Sakon

Tomoya Shiraki

Taiki Ishida

Soma Nagata

Yuji Kimura

Go Hamasaka

Yasuhiro Uozumi

Tsutomu Shinagawa

Osamu Shimomura

Ryoki Nomura

Affiliations

Soon will be listed here.

Abstract

The catalytic cycle of allylic arylation in water catalyzed by linear polystyrene-stabilized Pd or PdO nanoparticles (PS-PdNPs or PS-PdONPs) was investigated. Stoichiometric stepwise reactions indicated that the reaction did not proceed stepwise on the surface of the catalyst. In the case of the reaction with PS-PdNPs, the leached Pd species is the catalytically active species and the reaction takes place through a similar reaction pathway accepted in the case of a complex catalyst. In contrast, allylic arylation using PS-PdONPs as a catalyst occurs via a Pd catalytic cycle.

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