Superconductivity in the Surface State of Noble Metal Gold and Its Fermi Level Tuning by EuS Dielectric

The induced superconductivity (SC) in a robust and scalable quantum material with strong Rashba spin-orbit coupling is particularly attractive for generating topological superconductivity and Majorana bound states (MBS). Gold (111) thin film has been proposed as a promising candidate because of the large Rashba energy, the predicted topological nature, and the possibility for large-scale MBS device fabrications. We experimentally demonstrate two important steps towards achieving such a goal. We successfully show induced SC in the Shockley surface state (SS) of ultrathin Au(111) layers grown over epitaxial vanadium films, which is easily achievable on a wafer scale. The emergence of SC in the SS, which is physically separated from a bulk superconductor, is attained by indirect quasiparticle scattering processes instead of by conventional interfacial Andreev reflections. We further show the ability to tune the SS Fermi level (E_{F}) by interfacing SS with a high-κ dielectric ferromagnetic insulator EuS. The shift of E_{F} from ∼550 to ∼34  mV in superconducting SS is an important step towards realizing MBS in this robust system.