Symmetry-guided Syntheses of Mixed-linker Zr Metal-organic Frameworks with Precise Linker Locations

Overview

Journal Chem Sci

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2019 Jul 12

PMID 31293768

Citations 3

Authors

Hyehyun Kim

Dongwook Kim

Dohyun Moon

Yong Nam Choi

Seung Bin Baek

Myoung Soo Lah

Affiliations

Soon will be listed here.

Abstract

While the one-pot reaction of zirconium metal ions with a mixture of two dicarboxylate heterolinkers yielded a 12-c Zr MOF with randomly distributed linkers, the symmetry-guided stepwise reaction produced the same MOF with both linkers precisely located in the framework. In the latter method, linear terephthalic acid (HBDC) derivatives with symmetry were inserted into the -symmetry sites of the flexible Zr MOF with 8-c topology (), which is composed of zigzag 2,6-naphthalenedicarboxylic acid with 2/ symmetry. Although the length of the symmetry-matching BDC derivatives was much shorter than the distance between the unlinked nearest-neighbor Zr clusters in , induced fitting of the derivatives into the framework was possible, resulting in well-defined locations for the two different dicarboxylate linkers. Thus, controlled synthesis of MOFs with the desired topology and functionality can be achieved using a symmetry-guided approach.

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References

Cavka J, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S . A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. J Am Chem Soc. 2008; 130(42):13850-1. DOI: 10.1021/ja8057953. View

Deng H, Doonan C, Furukawa H, Ferreira R, Towne J, Knobler C . Multiple functional groups of varying ratios in metal-organic frameworks. Science. 2010; 327(5967):846-50. DOI: 10.1126/science.1181761. View

Garibay S, Cohen S . Isoreticular synthesis and modification of frameworks with the UiO-66 topology. Chem Commun (Camb). 2010; 46(41):7700-2. PMC: 3581306. DOI: 10.1039/c0cc02990d. View

Schaate A, Roy P, Godt A, Lippke J, Waltz F, Wiebcke M . Modulated synthesis of Zr-based metal-organic frameworks: from nano to single crystals. Chemistry. 2011; 17(24):6643-51. DOI: 10.1002/chem.201003211. View

Kim M, Cahill J, Prather K, Cohen S . Postsynthetic modification at orthogonal reactive sites on mixed, bifunctional metal-organic frameworks. Chem Commun (Camb). 2011; 47(27):7629-31. DOI: 10.1039/c1cc12101d. View

Cohen S . Postsynthetic methods for the functionalization of metal-organic frameworks. Chem Rev. 2011; 112(2):970-1000. DOI: 10.1021/cr200179u. View

Zhou H, Long J, Yaghi O . Introduction to metal-organic frameworks. Chem Rev. 2012; 112(2):673-4. DOI: 10.1021/cr300014x. View

Jiang H, Feng D, Liu T, Li J, Zhou H . Pore surface engineering with controlled loadings of functional groups via click chemistry in highly stable metal-organic frameworks. J Am Chem Soc. 2012; 134(36):14690-3. DOI: 10.1021/ja3063919. View

Cook T, Zheng Y, Stang P . Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials. Chem Rev. 2012; 113(1):734-77. PMC: 3764682. DOI: 10.1021/cr3002824. View

10.

Bunck D, Dichtel W . Mixed linker strategies for organic framework functionalization. Chemistry. 2013; 19(3):818-27. DOI: 10.1002/chem.201203145. View

11.

Furukawa H, Cordova K, OKeeffe M, Yaghi O . The chemistry and applications of metal-organic frameworks. Science. 2013; 341(6149):1230444. DOI: 10.1126/science.1230444. View

12.

Li L, Tang S, Wang C, Lv X, Jiang M, Wu H . High gas storage capacities and stepwise adsorption in a UiO type metal-organic framework incorporating Lewis basic bipyridyl sites. Chem Commun (Camb). 2014; 50(18):2304-7. DOI: 10.1039/c3cc48275h. View

13.

Karagiaridi O, Bury W, Mondloch J, Hupp J, Farha O . Solvent-assisted linker exchange: an alternative to the de novo synthesis of unattainable metal-organic frameworks. Angew Chem Int Ed Engl. 2014; 53(18):4530-40. DOI: 10.1002/anie.201306923. View

14.

Deria P, Mondloch J, Karagiaridi O, Bury W, Hupp J, Farha O . Beyond post-synthesis modification: evolution of metal-organic frameworks via building block replacement. Chem Soc Rev. 2014; 43(16):5896-912. DOI: 10.1039/c4cs00067f. View

15.

Wang C, Volotskova O, Lu K, Ahmad M, Sun C, Xing L . Synergistic assembly of heavy metal clusters and luminescent organic bridging ligands in metal-organic frameworks for highly efficient X-ray scintillation. J Am Chem Soc. 2014; 136(17):6171-4. PMC: 4017603. DOI: 10.1021/ja500671h. View

16.

Wang B, Huang H, Lv X, Xie Y, Li M, Li J . Tuning CO₂ selective adsorption over N₂ and CH₄ in UiO-67 analogues through ligand functionalization. Inorg Chem. 2014; 53(17):9254-9. DOI: 10.1021/ic5013473. View

17.

Yuan S, Lu W, Chen Y, Zhang Q, Liu T, Feng D . Sequential linker installation: precise placement of functional groups in multivariate metal-organic frameworks. J Am Chem Soc. 2015; 137(9):3177-80. DOI: 10.1021/ja512762r. View

18.

Marshall R, Griffin S, Wilson C, Forgan R . Single-Crystal to Single-Crystal Mechanical Contraction of Metal-Organic Frameworks through Stereoselective Postsynthetic Bromination. J Am Chem Soc. 2015; 137(30):9527-30. DOI: 10.1021/jacs.5b05434. View

19.

Bai Y, Dou Y, Xie L, Rutledge W, Li J, Zhou H . Zr-based metal-organic frameworks: design, synthesis, structure, and applications. Chem Soc Rev. 2016; 45(8):2327-67. DOI: 10.1039/c5cs00837a. View

20.

Yuan S, Chen Y, Qin J, Lu W, Zou L, Zhang Q . Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs. J Am Chem Soc. 2016; 138(28):8912-9. DOI: 10.1021/jacs.6b04501. View