Polymer Science and Engineering Using Deep Eutectic Solvents

Overview

Journal Polymers (Basel)

Publisher MDPI

Date 2019 May 24

PMID 31117221

Citations 16

Authors

Ana Roda

Ana A Matias

Alexandre Paiva

Ana Rita C Duarte

Affiliations

Soon will be listed here.

Abstract

The green and versatile character of deep eutectic solvents (DES) has turned them into significant tools in the development of green and sustainable technologies. For this purpose, their use in polymeric applications has been growing and expanding to new areas of development. The present review aims to summarize the progress in the field of DES applied to polymer science and engineering. It comprises fundamentals studies involving DES and polymers, recent applications of DES in polymer synthesis, extraction and modification, and the early developments on the formulation of DES-polymer products. The combination of DES and polymers is highly promising in the development of new and 'greener' materials. Still, there is plenty of room for future research in this field.

Citing Articles

Enhanced Chemical Stability of Tetramethylammonium Head Groups via Deep Eutectic Solvent: A Computational Study.

Karibayev M, Myrzakhmetov B, Wang Y, Mentbayeva A Molecules. 2024; 29(20).

PMID: 39459235 PMC: 11509940. DOI: 10.3390/molecules29204869.

Eutectic In Situ Modification of Polyamide 12 Processed through Laser-Based Powder Bed Fusion.

Schlicht S, Drummer D Materials (Basel). 2023; 16(5).

PMID: 36903165 PMC: 10003968. DOI: 10.3390/ma16052050.

Poly(3-hydroxybutyrate--3-hydroxyvalerate) Electrospun Nanofibers Containing Natural Deep Eutectic Solvents Exhibiting a 3D Rugose Morphology and Charge Retention Properties.

Basar A, Prieto C, Pardo-Figuerez M, Lagaron J ACS Omega. 2023; 8(4):3798-3811.

PMID: 36743045 PMC: 9893451. DOI: 10.1021/acsomega.2c05838.

Effects of Molecular Weight and Surface Interactions on Polymer Diffusion in Confinement.

Roopnarine B, Schmidt S, Maxwell K, Morozova S ACS Macro Lett. 2023; 12(2):221-226.

PMID: 36705547 PMC: 9948537. DOI: 10.1021/acsmacrolett.3c00015.

Controversy on the toxic nature of deep eutectic solvents and their potential contribution to environmental pollution.

Martinez G, Townley G, Martinez-Espinosa R Heliyon. 2023; 8(12):e12567.

PMID: 36619414 PMC: 9813709. DOI: 10.1016/j.heliyon.2022.e12567.

References

Abbott A, Capper G, Davies D, Rasheed R, Tambyrajah V . Novel solvent properties of choline chloride/urea mixtures. Chem Commun (Camb). 2003; (1):70-1. DOI: 10.1039/b210714g. View

Monnard P, Kanavarioti A, Deamer D . Eutectic phase polymerization of activated ribonucleotide mixtures yields quasi-equimolar incorporation of purine and pyrimidine nucleobases. J Am Chem Soc. 2003; 125(45):13734-40. DOI: 10.1021/ja036465h. View

Mota-Morales J, Gutierrez M, Sanchez I, Luna-Barcenas G, Del Monte F . Frontal polymerizations carried out in Deep-Eutectic mixtures providing both the monomers and the polymerization medium. Chem Commun (Camb). 2011; 47(18):5328-30. DOI: 10.1039/c1cc10391a. View

Choi Y, Van Spronsen J, Dai Y, Verberne M, Hollmann F, Arends I . Are natural deep eutectic solvents the missing link in understanding cellular metabolism and physiology?. Plant Physiol. 2011; 156(4):1701-5. PMC: 3149944. DOI: 10.1104/pp.111.178426. View

Freire M, Claudio A, Araujo J, Coutinho J, Marrucho I, Lopes J . Aqueous biphasic systems: a boost brought about by using ionic liquids. Chem Soc Rev. 2012; 41(14):4966-95. DOI: 10.1039/c2cs35151j. View

Carriazo D, Serrano M, Gutierrez M, Ferrer M, Del Monte F . Deep-eutectic solvents playing multiple roles in the synthesis of polymers and related materials. Chem Soc Rev. 2012; 41(14):4996-5014. DOI: 10.1039/c2cs15353j. View

Del Monte F, Carriazo D, Serrano M, Gutierrez M, Ferrer M . Deep eutectic solvents in polymerizations: a greener alternative to conventional syntheses. ChemSusChem. 2013; 7(4):999-1009. DOI: 10.1002/cssc.201300864. View

Sousa A, Souza H, Latona N, Liu C, Goncalves M, Liu L . Choline chloride based ionic liquid analogues as tool for the fabrication of agar films with improved mechanical properties. Carbohydr Polym. 2014; 111:206-14. DOI: 10.1016/j.carbpol.2014.04.019. View

Meng Y, Chen Y, Zhang Z, Lin Z, Tong M . Gadolinium oxalate derivatives with enhanced magnetocaloric effect via ionothermal synthesis. Inorg Chem. 2014; 53(17):9052-7. DOI: 10.1021/ic501013x. View

10.

Sousa A, Souza H, Uknalis J, Liu S, Goncalves M, Liu L . Improving agar electrospinnability with choline-based deep eutectic solvents. Int J Biol Macromol. 2015; 80:139-48. DOI: 10.1016/j.ijbiomac.2015.06.034. View

11.

Aroso I, Craveiro R, Rocha A, Dionisio M, Barreiros S, Reis R . Design of controlled release systems for THEDES-Therapeutic deep eutectic solvents, using supercritical fluid technology. Int J Pharm. 2015; 492(1-2):73-9. DOI: 10.1016/j.ijpharm.2015.06.038. View

12.

Li G, Wang W, Wang Q, Zhu T . Deep Eutectic Solvents Modified Molecular Imprinted Polymers for Optimized Purification of Chlorogenic Acid from Honeysuckle. J Chromatogr Sci. 2015; 54(2):271-9. DOI: 10.1093/chromsci/bmv138. View

13.

Zdanowicz M, Spychaj T, Maka H . Imidazole-based deep eutectic solvents for starch dissolution and plasticization. Carbohydr Polym. 2016; 140:416-23. DOI: 10.1016/j.carbpol.2015.12.036. View

14.

Sapir L, Stanley C, Harries D . Properties of Polyvinylpyrrolidone in a Deep Eutectic Solvent. J Phys Chem A. 2016; 120(19):3253-9. DOI: 10.1021/acs.jpca.5b11927. View

15.

Ashworth C, Matthews R, Welton T, Hunt P . Doubly ionic hydrogen bond interactions within the choline chloride-urea deep eutectic solvent. Phys Chem Chem Phys. 2016; 18(27):18145-60. DOI: 10.1039/c6cp02815b. View

16.

Zahn S, Kirchner B, Mollenhauer D . Charge Spreading in Deep Eutectic Solvents. Chemphyschem. 2016; 17(21):3354-3358. DOI: 10.1002/cphc.201600348. View

17.

Liu Y, Wang Y, Dai Q, Zhou Y . Magnetic deep eutectic solvents molecularly imprinted polymers for the selective recognition and separation of protein. Anal Chim Acta. 2016; 936:168-78. DOI: 10.1016/j.aca.2016.07.003. View

18.

Li G, Ahn W, Row K . Hybrid molecularly imprinted polymers modified by deep eutectic solvents and ionic liquids with three templates for the rapid simultaneous purification of rutin, scoparone, and quercetin from Herba Artemisiae Scopariae. J Sep Sci. 2016; 39(23):4465-4473. DOI: 10.1002/jssc.201600892. View

19.

Xu K, Wang Y, Li Y, Lin Y, Zhang H, Zhou Y . A novel poly(deep eutectic solvent)-based magnetic silica composite for solid-phase extraction of trypsin. Anal Chim Acta. 2016; 946:64-72. DOI: 10.1016/j.aca.2016.10.021. View

20.

Li G, Zhu T, Row K . Deep eutectic solvents for the purification of chloromycetin and thiamphenicol from milk. J Sep Sci. 2016; 40(3):625-634. DOI: 10.1002/jssc.201600771. View