Sorption and Desorption Studies of Pb(II) and Ni(II) from Aqueous Solutions by a New Composite Based on Alginate and Magadiite Materials

Overview

Journal Polymers (Basel)

Publisher MDPI

Date 2019 Apr 10

PMID 30960324

Citations 16

Authors

Keltoum Attar

Hary Demey

Djamila Bouazza

Ana Maria Sastre

Affiliations

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Abstract

A new composite material based on alginate and magadiite/Di-(2-ethylhexyl) phosphoric acid (CAM-D2EHPA) was successfully prepared by previous impregnation of layered magadiite with D2EHPA extractant, and then immobilized into the alginate matrix. Air dried beads of CAM-D2EHPA were characterized by FTIR and SEM⁻EDX techniques. The sorbent was used for the separation of lead and nickel from nitrate solutions; the main parameters of sorption such as contact time, pH of the solution, and initial metal concentration were studied. The beads recovered 94% of Pb(II) and 65% of Ni(II) at pH 4 from dilute solutions containing 10 mg L of metal (sorbent dosage, S.D. 1 g L). The equilibrium data gave a better fit using the Langmuir model, and kinetic profiles were fitted using a pseudo-second order rate equation. The maximum sorption capacities obtained (at pH 4) were 197 mg g and 44 mg g for lead and nickel, respectively. The regeneration of the sorbent was efficiently carried out with a dilute solution of HNO₃ (0.5 M). The composite material was reused in 10 sorption⁻elution cycles with no significant differences on sorption uptake. A study with synthetic effluents containing an equimolar concentration of both metals indicated a better selectivity towards lead ions.

Citing Articles

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