Rapid Monitoring of Organochlorine Pesticide Residues in Various Fruit Juices and Water Samples Using Fabric Phase Sorptive Extraction and Gas Chromatography-Mass Spectrometry

Overview

Journal Molecules

Publisher MDPI

Specialty Biology

Date 2019 Mar 16

PMID 30871257

Citations 2

Authors

Ramandeep Kaur

Ripneel Kaur

Susheela Rani

Ashok Kumar Malik

Abuzar Kabir

Kenneth G Furton

Victoria F Samanidou

Affiliations

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Abstract

Fabric phase sorptive extraction, an innovative integration of solid phase extraction and solid phase microextraction principles, has been combined with gas chromatography-mass spectrometry for the rapid extraction and determination of nineteen organochlorine pesticides in various fruit juices and water samples. FPSE consolidates the advanced features of sol-gel derived extraction sorbents with the rich surface chemistry of cellulose fabric substrate, which could extract the target analytes directly from the complex sample matrices, substantially simplifying the sample preparation operation. Important FPSE parameters, including sorbent chemistry, extraction time, stirring speed, type and volume of back-extraction solvent, and back-extraction time have been optimized. Calibration curves were obtained in a concentration range of 0.1⁻500 ng/mL. Under optimum conditions, limits of detection were obtained in a range of 0.007⁻0.032 ng/mL with satisfactory precision (RSD < 6%). The relative recoveries obtained by spiking organochlorine pesticides in water and selected juice samples were in the range of 91.56⁻99.83%. The sorbent sol-gel poly(ethylene glycol)-poly(propylene glycol)-poly(ethylene glycol) was applied for the extraction and preconcentration of organochlorine pesticides in aqueous and fruit juice samples prior to analysis with gas chromatography-mass spectrometry. The results demonstrated that the present method is simple, rapid, and precise for the determination of organochlorine pesticides in aqueous samples.

Citing Articles

New fabric phase sorptive extraction for nondestructive analysis of heritage textile samples.

Tanasescu E, Ene A, Perdum E, Iordache O, Secareanu L Heliyon. 2024; 10(10):e31020.

PMID: 38778962 PMC: 11108984. DOI: 10.1016/j.heliyon.2024.e31020.

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation.

Kabir A, Samanidou V Molecules. 2021; 26(4).

PMID: 33562079 PMC: 7915638. DOI: 10.3390/molecules26040865.

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