Synthesis and Characterization of Ni(II) Complex Functionalized Silica-based Magnetic Nanocatalyst and Its Application in C-N and C-C Cross-coupling Reactions

Overview

Journal Mol Divers

Date 2018 Nov 24

PMID 30467803

Citations 1

Authors

Mohaddeseh Shahabi Nejad

Neda Seyedi

Hassan Sheibani

Soheila Behzadi

Affiliations

Soon will be listed here.

Abstract

A new magnetically recoverable silica-based nickel(II) nanocatalyst was synthesized by a simple cost-effective procedure, which was characterized by TEM, SEM, XRD, VSM analysis, and FT-IR spectrophotometry. The catalytic activity of the prepared Ni(II) nanocatalyst was tested in two complementary reactions: C-N Chan-Lam cross-coupling of phenylboronic acid with aryl amines and C-C Suzuki-Miyaura cross-coupling reaction of phenylboronic acid with aryl halides. The catalyst was easily recovered by magnetic separation and reused for five times. It demonstrated better catalytic activity in the C-N Chan-Lam reaction compared to C-C Suzuki-Miyaura reaction. Ease of recovery and reusability up to five cycles without noticeable loss of performance in the C-N cross-coupling reaction make the present protocol beneficial both industrially and environmentally. In this paper, a new magnetically recoverable silica-based nickel(II) nanocatalyst was synthesized and applied in two complementary reactions: C-C Suzuki-Miyaura reaction and C-N Chan-Lam reaction. The difference in catalytic activity makes it possible to use this catalyst for cases that are prone to both reactions and selectively create the desired product.

Citing Articles

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PMID: 34694532 DOI: 10.1007/s11030-021-10339-8.

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