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Prussian Blue Analogs for Rechargeable Batteries

Overview
Journal iScience
Publisher Cell Press
Date 2018 Nov 15
PMID 30428315
Citations 26
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Abstract

Non-lithium energy storage devices, especially sodium ion batteries, are drawing attention due to insufficient and uneven distribution of lithium resources. Prussian blue and its analogs (Prussian blue analogs [PBAs]), or hexacyanoferrates, are well-known since the 18th century and have been used for hydrogen storage, cancer therapy, biosensing, seawater desalination, and sewage treatment. Owing to their unique features, PBAs are receiving increasing interest in the field of energy storage, such as their high theoretical specific capacity, ease of synthesis, as well as low cost. In this review, a general summary and evaluation of the applications of PBAs for rechargeable batteries are given. After a brief review of the history of PBAs, their crystal structure, nomenclature, synthesis, and working principle in rechargeable batteries are discussed. Then, previous works classified based on the combination of insertion cations and transition metals are analyzed comprehensively. The review includes an outlook toward the further development of PBAs in electrochemical energy storage.

Citing Articles

Dehydration Conditions and Ultrafast Rehydration of Prussian White: Phase Transition Dynamics and Implications for Sodium-Ion Batteries.

Clavelin A, Thanh D, Bobrikov I, Fehse M, Drewett N, Lopez G ACS Mater Lett. 2024; 6(11):5208-5214.

PMID: 39512726 PMC: 11539934. DOI: 10.1021/acsmaterialslett.4c01833.


A Self-Constructed Mg/K Co-Doped Prussian Blue with Superior Cycling Stability Enabled by Enhanced Coulombic Attraction.

Xu Z, Chen F, Li Y, Lu Y, Zhou A, Jiang J Adv Sci (Weinh). 2024; 11(42):e2406842.

PMID: 39301890 PMC: 11558122. DOI: 10.1002/advs.202406842.


Exploring Zinc-Doped Manganese Hexacyanoferrate as Cathode for Aqueous Zinc-Ion Batteries.

Beitia J, Ahedo I, Paredes J, Goikolea E, Ruiz de Larramendi I Nanomaterials (Basel). 2024; 14(13).

PMID: 38998697 PMC: 11243504. DOI: 10.3390/nano14131092.


The pressure response of Jahn-Teller-distorted Prussian blue analogues.

Bostrom H, Cairns A, Chen M, Daisenberger D, Ridley C, Funnell N Chem Sci. 2024; 15(9):3155-3164.

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Bias-free driven ion assisted photoelectrochemical system for sustainable wastewater treatment.

Dang Q, Zhang W, Liu J, Wang L, Wu D, Wang D Nat Commun. 2023; 14(1):8413.

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