Metal Sulfide Ion Exchangers: Superior Sorbents for the Capture of Toxic and Nuclear Waste-related Metal Ions

Overview

Journal Chem Sci

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2018 Aug 30

PMID 30155129

Citations 22

Authors

Manolis J Manos

Mercouri G Kanatzidis

Affiliations

Soon will be listed here.

Abstract

Metal sulfide ion-exchangers () represent a new addition to the field of ion exchange materials. This is a growing class of materials that display exceptional selectivity and rapid sorption kinetics for soft or relatively soft metal ions as a result of their soft basic frameworks. Without requiring functionalization, they outperform the most efficient sulfur-functionalized materials. This is the first review focusing on this class of materials; it covers the most important , focusing on their synthesis, structural features and ion-exchange chemistry. Furthermore, recent developments in the engineered and composite forms of are described. Future research opportunities are also discussed in the hope of inspiring additional scientists to engage in this new area of research on sulfidic ion-exchange materials.

Citing Articles

Selective Adsorption of Sr(II) from Aqueous Solution by NaFePOCO: Experimental and DFT Studies.

Xie Y, Wang X, Men J, Zhu M, Liang C, Ding H Molecules. 2024; 29(12).

PMID: 38930973 PMC: 11206743. DOI: 10.3390/molecules29122908.

Crystal Structure Complexity and Approximate Limits of Possible Crystal Structures Based on Symmetry-Normalized Volumes.

Tschauner O, Bermanec M Materials (Basel). 2024; 17(11).

PMID: 38893882 PMC: 11173925. DOI: 10.3390/ma17112618.

"Ion-imprinting" strategy towards metal sulfide scavenger enables the highly selective capture of radiocesium.

Tang J, Jia S, Liu J, Yang L, Sun H, Feng M Nat Commun. 2024; 15(1):4281.

PMID: 38769121 PMC: 11106286. DOI: 10.1038/s41467-024-48565-x.

Layered metal sulfides with MS framework (M = Sb, In, Sn) as ion exchangers for the removal of Cs(Ⅰ) and Sr(Ⅱ) from radioactive effluents: a review.

Zhao Q, Wang S, Wu Y, Wang Y, Ma S, Shih K Front Chem. 2023; 11:1292979.

PMID: 38124703 PMC: 10730671. DOI: 10.3389/fchem.2023.1292979.

Efficient Removal of Pb(Ⅱ) by Highly Porous Polymeric Sponges Self-Assembled from a Poly(Amic Acid).

Leng Y, Jin K, Wang T, Lai X, Sun H Molecules. 2023; 28(7).

PMID: 37049658 PMC: 10095650. DOI: 10.3390/molecules28072897.

References

Sengupta P, Dudwadkar N, Vishwanadh B, Pulhani V, Rao R, Tripathi S . Uptake of hazardous radionuclides within layered chalcogenide for environmental protection. J Hazard Mater. 2014; 266:94-101. DOI: 10.1016/j.jhazmat.2013.12.010. View

Ma L, Wang Q, Islam S, Liu Y, Ma S, Kanatzidis M . Highly Selective and Efficient Removal of Heavy Metals by Layered Double Hydroxide Intercalated with the MoS4(2-) Ion. J Am Chem Soc. 2016; 138(8):2858-66. DOI: 10.1021/jacs.6b00110. View

Subrahmanyam K, Malliakas C, Sarma D, Armatas G, Wu J, Kanatzidis M . Ion-Exchangeable Molybdenum Sulfide Porous Chalcogel: Gas Adsorption and Capture of Iodine and Mercury. J Am Chem Soc. 2015; 137(43):13943-8. DOI: 10.1021/jacs.5b09110. View

Yuhas B, Smeigh A, Samuel A, Shim Y, Bag S, Douvalis A . Biomimetic multifunctional porous chalcogels as solar fuel catalysts. J Am Chem Soc. 2011; 133(19):7252-5. DOI: 10.1021/ja111275t. View

Du X, Zhang H, Hao X, Guan G, Abudula A . Facile preparation of ion-imprinted composite film for selective electrochemical removal of nickel(II) ions. ACS Appl Mater Interfaces. 2014; 6(12):9543-9. DOI: 10.1021/am501926u. View

Zhang B, Feng M, Cui H, Du C, Qi X, Shen N . Syntheses, Crystal Structures, Ion-Exchange, and Photocatalytic Properties of Two Amine-Directed Ge-Sb-S Compounds. Inorg Chem. 2015; 54(17):8474-81. DOI: 10.1021/acs.inorgchem.5b01181. View

Xiong W, Miao J, Ye K, Wang Y, Liu B, Zhang Q . Threading chalcogenide layers with polymer chains. Angew Chem Int Ed Engl. 2014; 54(2):546-50. DOI: 10.1002/anie.201409653. View

Manos M, Chrissafis K, Kanatzidis M . Unique pore selectivity for Cs+ and exceptionally high NH4+ exchange capacity of the chalcogenide material K6Sn[Zn4Sn4S17]. J Am Chem Soc. 2006; 128(27):8875-83. DOI: 10.1021/ja061342t. View

Benhammou A, Yaacoubi A, Nibou L, Tanouti B . Adsorption of metal ions onto Moroccan stevensite: kinetic and isotherm studies. J Colloid Interface Sci. 2004; 282(2):320-6. DOI: 10.1016/j.jcis.2004.08.168. View

10.

Oh Y, Morris C, Kanatzidis M . Polysulfide chalcogels with ion-exchange properties and highly efficient mercury vapor sorption. J Am Chem Soc. 2012; 134(35):14604-8. DOI: 10.1021/ja3061535. View

11.

Biswas K, Zhang Q, Chung I, Song J, Androulakis J, Freeman A . Synthesis in ionic liquids: [Bi2Te2Br](AlCl4), a direct gap semiconductor with a cationic framework. J Am Chem Soc. 2010; 132(42):14760-2. DOI: 10.1021/ja107483g. View

12.

Rapti S, Pournara A, Sarma D, Papadas I, Armatas G, Tsipis A . Selective capture of hexavalent chromium from an anion-exchange column of metal organic resin-alginic acid composite. Chem Sci. 2018; 7(3):2427-2436. PMC: 6004612. DOI: 10.1039/c5sc03732h. View

13.

Manos M, Iyer R, Quarez E, Liao J, Kanatzidis M . {Sn[Zn4Sn4S17]}6-: a robust open framework based on metal-linked penta-supertetrahedral [Zn4Sn4S17]10- clusters with ion-exchange properties. Angew Chem Int Ed Engl. 2005; 44(23):3552-5. DOI: 10.1002/anie.200500214. View

14.

Yee K, Reimer N, Liu J, Cheng S, Yiu S, Weber J . Effective mercury sorption by thiol-laced metal-organic frameworks: in strong acid and the vapor phase. J Am Chem Soc. 2013; 135(21):7795-8. DOI: 10.1021/ja400212k. View

15.

Manos M, Kanatzidis M . Highly efficient and rapid Cs+ uptake by the layered metal sulfide K(2x)Mn(x)Sn(3-x)S(6) (KMS-1). J Am Chem Soc. 2009; 131(18):6599-607. DOI: 10.1021/ja900977p. View

16.

Zhang G, Li P, Ding J, Liu Y, Xiong W, Nie L . Surfactant-thermal syntheses, structures, and magnetic properties of Mn-Ge-sulfides/selenides. Inorg Chem. 2014; 53(19):10248-56. DOI: 10.1021/ic501282d. View

17.

Mohanan J, Arachchige I, Brock S . Porous semiconductor chalcogenide aerogels. Science. 2005; 307(5708):397-400. DOI: 10.1126/science.1106525. View

18.

Li , LAINE , OKeeffe , Yaghi . Supertetrahedral sulfide crystals with giant cavities and channels . Science. 1999; 283(5405):1145-7. DOI: 10.1126/science.283.5405.1145. View

19.

Pearson R . Acids and bases. Science. 1966; 151(3707):172-7. DOI: 10.1126/science.151.3707.172. View

20.

Ma S, Huang L, Ma L, Shim Y, Islam S, Wang P . Efficient uranium capture by polysulfide/layered double hydroxide composites. J Am Chem Soc. 2015; 137(10):3670-7. DOI: 10.1021/jacs.5b00762. View