Organometallic-Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu Ions

Overview

Journal Eur J Inorg Chem

Date 2018 Jul 24

PMID 30034271

Citations 3

Authors

Mehdi Elsayed Moussa

Stefan Welsch

Matthias Lochner

Eugenia V Peresypkina

Alexander V Virovets

Manfred Scheer

Affiliations

Soon will be listed here.

Abstract

A multicomponent approach of the P ligand complex [Cp*Fe(η-P)] (: Cp* = η-CMe) with the ditopic organic linkers 4,4'-bipyridine () or -1,2-di(pyridine-4-yl)ethene () in the presence of Cu salts of the anions [BF] and [PF] or the coordinating anion Br, leads to the formation of four novel organometallic-organic hybrid polymers: the cationic 1D polymeric compounds [Cu{Cp*Fe(µ,η-P)}(µ,η-CHN)(CHCN)] [BF] () and [Cu{Cp*Fe(µ,η-P)}(µ,η-CHN)(CHCN)] [PF] () as well as the unique neutral threefold 2D → 2D interpenetrated networks [CuCl{Cp*Fe(µ,η-P)}(µ,η-CHN)] () and [CuBr{Cp*Fe(µ,η-P)}(µ,η-CHN)] ().

Citing Articles

Mixed Organometallic-Organic Hybrid Assemblies Based on the Diarsene Complex [Cp Mo (CO) (μ,η -As )], Ag Salts and N-Donor Organic Molecules.

Elsayed Moussa M, Shelyganov P, Seidl M, Peresypkina E, Berg N, Gschwind R Chemistry. 2021; 27(15):5028-5034.

PMID: 33400327 PMC: 7986401. DOI: 10.1002/chem.202100027.

Linking of Cu Units by Tetrahedral Mo E Complexes (E=P, As).

Schiller J, Schreiner A, Seidl M, Balazs G, Scheer M Chemistry. 2020; 26(64):14570-14574.

PMID: 32614109 PMC: 7756472. DOI: 10.1002/chem.202003133.

The Triple-Decker Complex [Cp*Fe(µ,η⁵:η⁵-P₅)Mo(CO)₃] as a Building Block in Coordination Chemistry.

Elsayed Moussa M, Welsch S, Dutsch L, Piesch M, Reichl S, Seidl M Molecules. 2019; 24(2).

PMID: 30658411 PMC: 6358725. DOI: 10.3390/molecules24020325.

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