Chirality Sensing of Choline Derivatives by a Triple Anion Helicate Cage Through Induced Circular Dichroism

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2018 Jun 19

PMID 29911235

Citations 7

Authors

Wei Zuo

Zhe Huang

Yanxia Zhao

Wenhua Xu

Zhihua Liu

Xiao-Juan Yang

Chuandong Jia

Biao Wu

Affiliations

Soon will be listed here.

Abstract

Chirality sensing of choline derivatives is achieved by a self-assembled, racemic triple anion helicate cage which exhibits induced circular dichroism (ICD) upon encapsulation of a chiral guest. The host-guest interactions were illustrated by NMR, crystal structure, CD and DFT calculations. The absolute configurations and ee values were determined by ICD.

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