Adducts of Triallylborane with Ammonia and Aliphatic Amines As Stoichiometric Allylating Agents for Aminoallylation Reaction of Carbonyl Compounds

Overview

Journal Org Lett

Publisher American Chemical Society

Specialties Biochemistry
Chemistry

Date 2018 Jun 7

PMID 29873233

Citations 3

Authors

Nikolai Yu Kuznetsov

Rabdan M Tikhov

Tatiana V Strelkova

Yuri N Bubnov

Affiliations

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Abstract

Triallylborane-amines adducts are effective stoichiometric allylating agents in the aminoallylation reaction of carbonyl compounds in methanol. Moreover, copper-catalyzed diastereoselective allylation of Ellman's imine was achieved with triallylborane-methylamine adduct.

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