Sorption of Antibiotics Onto Montmorillonite and Kaolinite: Competition Modelling

Antibiotic contaminants, which are generally present in bi-solute systems, can be competitively adsorbed onto clays. Single- and bi-solute sorptions of sulfadiazine (SDZ) and ciprofloxacin (CIP) onto montmorillonite and kaolinite were investigated at pH values of 5 and 8. Freundlich and Langmuir models were used and fit the experimental data well for single-solute sorption. The sorption isotherms were nonlinear ( = 0.265-0.730), and the maximum sorption capacities () of the SDZ and CIP onto montmorillonite were higher than those onto kaolinite. The octanol-water distribution ratio (), cation exchange capacity (CEC), Brunauer-Emmett-Teller (BET) surface area (A), pore size, point of zero charge (pH), and basal spacing predominantly affected the Freundlich constant () and of SDZ and CIP at pH 5 more than SDZ and CIP at pH 8. For bi-solute sorption, the presence of CIP inhibited the SDZ sorption onto montmorillonite and kaolinite. Competitive sorption models such as Sheindorf-Rebhun-Sheintuch (SRS), Murali-Aylmore (M-A) and the modified extended Langmuir model (MELM) were used; of these, the MELM provided the best prediction with SDZ sorption onto montmorillonite at pH 8 and CIP onto kaolinite at pH 5 and 8 in SDZ/CIP system occurring synergistically, whereas others occurred antagonistically. The distribution coefficient () of the bi-solute sorption decreased with increasing pH in the order cationic > neutral > anionic for SDZ and cationic > zwitterionic > anionic for CIP, which resembled the of single-solute sorption. Fourier transform spectroscopy (FT-IR) spectra indicated that amine in SDZ and keto oxygen in CIP were responsible for the interactions with the montmorillonite and kaolinite.