Novel, One-step Synthesis of Zwitterionic Polymer Nanoparticles Via Distillation-precipitation Polymerization and Its Application for Dye Removal Membrane

Overview

Journal Sci Rep

Specialty Science

Date 2017 Nov 23

PMID 29162869

Citations 15

Authors

G P Syed Ibrahim

Arun M Isloor

Inamuddin

Abdullah M Asiri

Norafiqah Ismail

Ahmed Fauzi Ismail

Ghulam Md Ashraf

Affiliations

Soon will be listed here.

Abstract

In this work, poly(MBAAm-co-SBMA) zwitterionic polymer nanoparticles were synthesized in one-step via distillation-precipitation polymerization (DPP) and were characterized. [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA) as monomer and N, N'-methylene bis(acrylamide) (MBAAm) as cross-linker are used for the synthesis of nanoparticles. As far as our knowledge, this is the first such report on the synthesis of poly(MBAAm-co-SBMA) nanoparticles via DPP. The newly synthesized nanoparticles were further employed for the surface modification of polysulfone (PSF) hollow fiber membranes for dye removal. The modified hollow fiber membrane exhibited the improved permeability (56 L/ m h bar) and dye removal (>98% of Reactive Black 5 and >80.7% of Reactive orange 16) with the high permeation of salts. Therefore, the as-prepared membrane can have potential application in textile and industrial wastewater treatment.

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