Self-template Synthesis of Biomass-derived 3D Hierarchical N-doped Porous Carbon for Simultaneous Determination of Dihydroxybenzene Isomers

Overview

Journal Sci Rep

Specialty Science

Date 2017 Nov 5

PMID 29101387

Citations 4

Authors

Dejian Chen

Haifeng Zhou

Hao Li

Jie Chen

Shunxing Li

Fengying Zheng

Affiliations

Soon will be listed here.

Abstract

Nitrogen doped hierarchical porous carbon materials (HPCs) was achieved by the successful carbonization, using pig lung as biomass precursor. Three-dimensional HPCs constituted with sheets and lines were synergistically inherited from original pig lung. Such structure provided a large specific surface area (958.5 g m) and rich porous, effectively supported a large number of electro-active species, and greatly enhanced the mass and electron transfer. High graphitization degree of HPCs resulted in good electrical conductivity. Furthermore, the different electronegativity between nitrogen and carbon atoms in HPCs could affect the electron cloud distribution, polarity and then the electrochemical oxidation kinetics of dihydroxybenzene isomers. Based on these characteristics of HPCs, the electrochemical sensor for dihydroxybenzene isomers exhibited high sensitivity, excellent specificity and stability. Quantitative analysis assays by differential pulse voltammetry (DPV) technology showed that the sensor has wide linear ranges (0.5-320, 0.5-340 and 1-360 μmol L) and low detection limits (0.078, 0.057 and 0.371 μmol L) for the catechol, resorcinol and hydroquinone, respectively. This proposed method was successfully applied for simultaneous detection of dihydroxybenzene isomers in river water.

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