Catalyst Free Annulative Thioboration of Unfunctionalized Olefins

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2017 Oct 27

PMID 29071315

Citations 1

Authors

Zhantao Yang

Chun-Hua Yang

Shiqi Chen

Xixi Chen

Litian Zhang

Huijun Ren

Affiliations

Soon will be listed here.

Abstract

A direct and catalyst-free annulative thioboration of unfunctionalized olefins has been developed. In the presence of BCl as the sole boron source, the boryl group and thiol group are added to the C-C double bonds simultaneously. The boronic acids obtained can be protected to form synthetically ubiquitous pinacol boronate esters.

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