Reduced Magnetism in Core-Shell Magnetite@MOF Composites
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The magnetic susceptibility of synthesized magnetite (FeO) microspheres was found to decline after the growth of a metal-organic framework (MOF) shell on the magnetite core. Detailed structural analysis of the core-shell particles using scanning electron microscopy, transmission electron microscopy, atom probe tomography, andFe-Mössbauer spectroscopy suggests that the distribution of MOF precursors inside the magnetic core resulted in the oxidation of the iron oxide core.
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