» Articles » PMID: 29026118

Coherent Coupling Between Vanadyl Phthalocyanine Spin Ensemble and Microwave Photons: Towards Integration of Molecular Spin Qubits into Quantum Circuits

Overview
Journal Sci Rep
Specialty Science
Date 2017 Oct 14
PMID 29026118
Citations 8
Authors
Affiliations
Soon will be listed here.
Abstract

Electron spins are ideal two-level systems that may couple with microwave photons so that, under specific conditions, coherent spin-photon states can be realized. This represents a fundamental step for the transfer and the manipulation of quantum information. Along with spin impurities in solids, molecular spins in concentrated phases have recently shown coherent dynamics under microwave stimuli. Here we show that it is possible to obtain high cooperativity regime between a molecular Vanadyl Phthalocyanine (VOPc) spin ensemble and a high quality factor superconducting YBaCuO (YBCO) coplanar resonator at 0.5 K. This demonstrates that molecular spin centers can be successfully integrated in hybrid quantum devices.

Citing Articles

Localized Nanoscale Formation of Vanadyl Porphyrin 2D MOF Nanosheets and Their Optimal Coupling to Lumped Element Superconducting Resonators.

Gimeno I, Luis F, Marcuello C, Pallares M, Lostao A, de Ory M J Phys Chem C Nanomater Interfaces. 2025; 129(1):973-982.

PMID: 39811435 PMC: 11726679. DOI: 10.1021/acs.jpcc.4c07265.


Theory of Magnetic Properties in Quantum Electrodynamics Environments: Application to Molecular Aromaticity.

Barlini A, Bianchi A, Ronca E, Koch H J Chem Theory Comput. 2024; .

PMID: 39255400 PMC: 11428136. DOI: 10.1021/acs.jctc.4c00195.


Gadolinium Spin Decoherence Mechanisms at High Magnetic Fields.

Wilson C, Qi M, Han S, Sherwin M J Phys Chem Lett. 2023; 14(47):10578-10584.

PMID: 37976425 PMC: 10694812. DOI: 10.1021/acs.jpclett.3c01847.


Recent advances in microresonators and supporting instrumentation for electron paramagnetic resonance spectroscopy.

Abhyankar N, Agrawal A, Campbell J, Maly T, Shrestha P, Szalai V Rev Sci Instrum. 2022; 93(10):101101.

PMID: 36319314 PMC: 9632321. DOI: 10.1063/5.0097853.


Orienting dilute thin films of non-planar spin-1/2 vanadyl-phthalocyanine complexes.

Xu Z, Romankov V, Doll A, Dreiser J Mater Adv. 2022; 3(12):4938-4946.

PMID: 35812836 PMC: 9207598. DOI: 10.1039/d2ma00157h.


References
1.
Schuster D, Sears A, Ginossar E, DiCarlo L, Frunzio L, Morton J . High-cooperativity coupling of electron-spin ensembles to superconducting cavities. Phys Rev Lett. 2011; 105(14):140501. DOI: 10.1103/PhysRevLett.105.140501. View

2.
Mi X, Cady J, Zajac D, Deelman P, Petta J . Strong coupling of a single electron in silicon to a microwave photon. Science. 2016; 355(6321):156-158. DOI: 10.1126/science.aal2469. View

3.
Warner M, Din S, Tupitsyn I, Morley G, Stoneham A, Gardener J . Potential for spin-based information processing in a thin-film molecular semiconductor. Nature. 2013; 503(7477):504-8. DOI: 10.1038/nature12597. View

4.
Julsgaard B, Grezes C, Bertet P, Molmer K . Quantum memory for microwave photons in an inhomogeneously broadened spin ensemble. Phys Rev Lett. 2013; 110(25):250503. DOI: 10.1103/PhysRevLett.110.250503. View

5.
Bertaina S, Gambarelli S, Tkachuk A, Kurkin I, Malkin B, Stepanov A . Rare-earth solid-state qubits. Nat Nanotechnol. 2008; 2(1):39-42. DOI: 10.1038/nnano.2006.174. View