Exceptional CO Working Capacity in a Heterodiamine-grafted Metal-organic Framework

Overview

Journal Chem Sci

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2017 Jul 15

PMID 28706716

Citations 22

Authors

Woo Ram Lee

HyunA Jo

Li-Ming Yang

Hanyeong Lee

Dae Won Ryu

Kwang Soo Lim

Jeong Hwa Song

Da Young Min

Sang Soo Han

Jeong Gil Seo

Yong Ki Park

Dohyun Moon

Chang Seop Hong

Affiliations

Soon will be listed here.

Abstract

An amine-functionalized metal-organic framework (MOF), dmen-Mg(dobpdc) (dmen = ,-dimethylethylenediamine), which contains a heterodiamine with both primary and tertiary amines, was prepared a post-synthetic method. This material exhibits a significant selectivity factor for CO over N that is commensurate with top-performing MOFs. It is remarkable that the solid is fully regenerated under vacuum or flowing Ar at low desorption temperatures, and following this can take up CO at more than 13 wt%. An exceptionally high working capacity is achieved at low regeneration temperatures and after exposure to humid conditions, which are important parameters for a real post-combustion CO capture process.

Citing Articles

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