Carbon Dots in Zeolites: A New Class of Thermally Activated Delayed Fluorescence Materials with Ultralong Lifetimes

Overview

Journal Sci Adv

Specialties Biology
Science

Date 2017 Jun 1

PMID 28560347

Citations 41

Authors

Jiancong Liu

Ning Wang

Yue Yu

Yan Yan

Hongyue Zhang

Jiyang Li

Jihong Yu

Affiliations

Soon will be listed here.

Abstract

Thermally activated delayed fluorescence (TADF) materials are inspiring intensive research in optoelectronic applications. To date, most of the TADF materials are limited to metal-organic complexes and organic molecules with lifetimes of several microseconds/milliseconds that are sensitive to oxygen. We report a facial and general "dots-in-zeolites" strategy to in situ confine carbon dots (CDs) in zeolitic matrices during hydrothermal/solvothermal crystallization to generate high-efficient TADF materials with ultralong lifetimes. The resultant CDs@zeolite composites exhibit high quantum yields up to 52.14% and ultralong lifetimes up to 350 ms at ambient temperature and atmosphere. This intriguing TADF phenomenon is due to the fact that nanoconfined space of zeolites can efficiently stabilize the triplet states of CDs, thus enabling the reverse intersystem crossing process for TADF. Meanwhile, zeolite frameworks can also hinder oxygen quenching to present TADF behavior at air atmosphere. This design concept introduces a new perspective to develop materials with unique TADF performance and various novel delayed fluorescence-based applications.

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References

Hou J, Wang L, Zhang P, Xu Y, Ding L . Facile synthesis of carbon dots in an immiscible system with excitation-independent emission and thermally activated delayed fluorescence. Chem Commun (Camb). 2015; 51(100):17768-71. DOI: 10.1039/c5cc08152a. View

Zhu S, Meng Q, Wang L, Zhang J, Song Y, Jin H . Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging. Angew Chem Int Ed Engl. 2013; 52(14):3953-7. DOI: 10.1002/anie.201300519. View

Wang Z, Yu J, Xu R . Needs and trends in rational synthesis of zeolitic materials. Chem Soc Rev. 2011; 41(5):1729-41. DOI: 10.1039/c1cs15150a. View

Zhang Q, Kuwabara H, Potscavage Jr W, Huang S, Hatae Y, Shibata T . Anthraquinone-based intramolecular charge-transfer compounds: computational molecular design, thermally activated delayed fluorescence, and highly efficient red electroluminescence. J Am Chem Soc. 2014; 136(52):18070-81. DOI: 10.1021/ja510144h. View

Xu S, Chen R, Zheng C, Huang W . Excited State Modulation for Organic Afterglow: Materials and Applications. Adv Mater. 2016; 28(45):9920-9940. DOI: 10.1002/adma.201602604. View

Lu G, Li S, Guo Z, Farha O, Hauser B, Qi X . Imparting functionality to a metal-organic framework material by controlled nanoparticle encapsulation. Nat Chem. 2012; 4(4):310-6. DOI: 10.1038/nchem.1272. View

Tao Y, Yuan K, Chen T, Xu P, Li H, Chen R . Thermally activated delayed fluorescence materials towards the breakthrough of organoelectronics. Adv Mater. 2014; 26(47):7931-58. DOI: 10.1002/adma.201402532. View

Yu J, Xu R . Rational approaches toward the design and synthesis of zeolitic inorganic open-framework materials. Acc Chem Res. 2010; 43(9):1195-204. DOI: 10.1021/ar900293m. View

Lee S, Yasuda T, Yang Y, Zhang Q, Adachi C . Luminous butterflies: efficient exciton harvesting by benzophenone derivatives for full-color delayed fluorescence OLEDs. Angew Chem Int Ed Engl. 2014; 53(25):6402-6. DOI: 10.1002/anie.201402992. View

10.

Wang S, Yan X, Cheng Z, Zhang H, Liu Y, Wang Y . Highly Efficient Near-Infrared Delayed Fluorescence Organic Light Emitting Diodes Using a Phenanthrene-Based Charge-Transfer Compound. Angew Chem Int Ed Engl. 2015; 54(44):13068-72. DOI: 10.1002/anie.201506687. View

11.

Pan L, Sun S, Zhang A, Jiang K, Zhang L, Dong C . Truly Fluorescent Excitation-Dependent Carbon Dots and Their Applications in Multicolor Cellular Imaging and Multidimensional Sensing. Adv Mater. 2015; 27(47):7782-7. DOI: 10.1002/adma.201503821. View

12.

Feng G, Cheng P, Yan W, Boronat M, Li X, Su J . Accelerated crystallization of zeolites via hydroxyl free radicals. Science. 2016; 351(6278):1188-91. DOI: 10.1126/science.aaf1559. View

13.

Fenwick O, Coutino-Gonzalez E, Grandjean D, Baekelant W, Richard F, Bonacchi S . Tuning the energetics and tailoring the optical properties of silver clusters confined in zeolites. Nat Mater. 2016; 15(9):1017-22. DOI: 10.1038/nmat4652. View

14.

Nakanotani H, Higuchi T, Furukawa T, Masui K, Morimoto K, Numata M . High-efficiency organic light-emitting diodes with fluorescent emitters. Nat Commun. 2014; 5:4016. DOI: 10.1038/ncomms5016. View

15.

Li J, Nakagawa T, MacDonald J, Zhang Q, Nomura H, Miyazaki H . Highly efficient organic light-emitting diode based on a hidden thermally activated delayed fluorescence channel in a heptazine derivative. Adv Mater. 2013; 25(24):3319-23. DOI: 10.1002/adma.201300575. View

16.

Bergmann L, Hedley G, Baumann T, Brase S, Samuel I . Direct observation of intersystem crossing in a thermally activated delayed fluorescence copper complex in the solid state. Sci Adv. 2016; 2(1):e1500889. PMC: 4705038. DOI: 10.1126/sciadv.1500889. View

17.

Li J, Corma A, Yu J . Synthesis of new zeolite structures. Chem Soc Rev. 2015; 44(20):7112-27. DOI: 10.1039/c5cs00023h. View

18.

Lim S, Shen W, Gao Z . Carbon quantum dots and their applications. Chem Soc Rev. 2014; 44(1):362-81. DOI: 10.1039/c4cs00269e. View

19.

Jiang K, Zhang L, Lu J, Xu C, Cai C, Lin H . Triple-Mode Emission of Carbon Dots: Applications for Advanced Anti-Counterfeiting. Angew Chem Int Ed Engl. 2016; 55(25):7231-5. DOI: 10.1002/anie.201602445. View

20.

Zhang Q, Li J, Shizu K, Huang S, Hirata S, Miyazaki H . Design of efficient thermally activated delayed fluorescence materials for pure blue organic light emitting diodes. J Am Chem Soc. 2012; 134(36):14706-9. DOI: 10.1021/ja306538w. View