A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units

Overview

Journal Nanomaterials (Basel)

Date 2017 Apr 22

PMID 28430135

Citations 3

Authors

Kun Cai

Nian Zhao

Ning Zhang

Fu-Xing Sun

Qing Zhao

Guang-Shan Zhu

Affiliations

Soon will be listed here.

Abstract

A new homochiral multifunctional metal-organic framework, [Zn₂(CTBA)₂·H₂O] (JUC-112), was synthesized under solvothermal conditions, through the design of chiral ligand 4-(3-carboxy-2,2,3-trimethylcyclopentanecarboxamido) benzoic acid (H₂CTBA) based on camphoric acid as building block. The crystal structure of the new material is a 2-dimensional (2D) chiral layer packed with infinite rod-shaped secondary building units (SBUs). The homochiral framework was identified by circular dichroism (CD) spectrum. Thermogravimetric measurement indicates its high thermal stability up to 450 °C. In addition, JUC-112 exhibits the capability of separating water from alcohols, second-order nonlinear optical effect, and photoluminescence.

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