New Chemical and Stereochemical Applications of Organoiron Complexes

Overview

Journal J Res Natl Inst Stand Technol

Date 2017 Feb 11

PMID 28184103

Authors

Alexander J Fatiadi

Affiliations

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Abstract

The objective of this review is to provide a current overview of the rapidly developing chemistry of organometallic complexes and particularly organoiron complexes useful in asymmetric and stereoselective reactions. Also covered are stereoselective reactions of α, β-unsaturated acyl ligands bound to the chiral auxiliary [(η-CH) Fe(CO)(PPh)] and new applications of organoiron complexes in the synthesis of natural products. The mechanistic aspects and stabilizing effects of the Fe(CO) group for alkenes or conjugated dienes are discussed. A brief summary of recent work on the special role of iron in biological reactions is also included.

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