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Z-Scheme Photocatalytic Systems for Promoting Photocatalytic Performance: Recent Progress and Future Challenges

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Journal Adv Sci (Weinh)
Date 2016 Dec 17
PMID 27980982
Citations 43
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Abstract

Semiconductor photocatalysts have attracted increased attention due to their great potential for solving energy and environmental problems. The formation of Z-scheme photocatalytic systems that mimic natural photosynthesis is a promising strategy to improve photocatalytic activity that is superior to single component photocatalysts. The connection between photosystem I (PS I) and photosystem II (PS II) are crucial for constructing efficient Z-scheme photocatalytic systems using two photocatalysts (PS I and PS II). The present review concisely summarizes and highlights recent state-of-the-art accomplishments of Z-scheme photocatalytic systems with diverse connection modes, including i) with shuttle redox mediators, ii) without electron mediators, and iii) with solid-state electron mediators, which effectively increase visible-light absorption, promote the separation and transportation of photoinduced charge carriers, and thus enhance the photocatalytic efficiency. The challenges and prospects for future development of Z-scheme photocatalytic systems are also presented.

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References
1.
Tabata M, Maeda K, Higashi M, Lu D, Takata T, Abe R . Modified Ta3N5 powder as a photocatalyst for O2 evolution in a two-step water splitting system with an iodate/iodide shuttle redox mediator under visible light. Langmuir. 2010; 26(12):9161-5. DOI: 10.1021/la100722w. View

2.
Umena Y, Kawakami K, Shen J, Kamiya N . Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å. Nature. 2011; 473(7345):55-60. DOI: 10.1038/nature09913. View

3.
Zhang Z, Jiang D, Xing C, Chen L, Chen M, He M . Novel AgI-decorated β-Bi₂O₃ nanosheet heterostructured Z-scheme photocatalysts for efficient degradation of organic pollutants with enhanced performance. Dalton Trans. 2015; 44(25):11582-91. DOI: 10.1039/c5dt00298b. View

4.
Shifu C, Lei J, Wenming T, Xianliang F . Fabrication, characterization and mechanism of a novel Z-scheme photocatalyst NaNbO3/WO3 with enhanced photocatalytic activity. Dalton Trans. 2013; 42(30):10759-68. DOI: 10.1039/c3dt50699a. View

5.
Tu W, Zhou Y, Zou Z . Photocatalytic conversion of CO(2) into renewable hydrocarbon fuels: state-of-the-art accomplishment, challenges, and prospects. Adv Mater. 2014; 26(27):4607-26. DOI: 10.1002/adma.201400087. View