Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates Through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling

Overview

Journal Chemistry

Specialty Chemistry

Date 2016 Sep 24

PMID 27661773

Citations 11

Authors

Lulu Fan

Jiaqi Jia

Hong Hou

Quentin Lefebvre

Magnus Rueping

Affiliations

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Abstract

A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C-O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.

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