Photochemical Synthesis of Carbazoles Using an [Fe(phen)](NTf)/O Catalyst System: Catalysis Toward Sustainability
Overview
Chemistry
Affiliations
An increasingly sustainable photochemical synthesis of carbazoles was developed using a catalytic system of Fe(phen)(NTf)/O under continuous flow conditions and was demonstrated on gram-scale using a numbering-up strategy. Photocyclization of triaryl and diarylamines into the corresponding carbazoles occurs in general in higher yields than with previously developed photocatalysts.
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Hao H, Manssen M, Schafer L Chem Sci. 2023; 14(18):4928-4934.
PMID: 37181785 PMC: 10171191. DOI: 10.1039/d3sc00042g.
Iron Photoredox Catalysis-Past, Present, and Future.
de Groot L, Ilic A, Schwarz J, Warnmark K J Am Chem Soc. 2023; 145(17):9369-9388.
PMID: 37079887 PMC: 10161236. DOI: 10.1021/jacs.3c01000.
Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d Complexes with Cr, Mn, Fe, and Co.
Sinha N, Wenger O J Am Chem Soc. 2023; 145(9):4903-4920.
PMID: 36808978 PMC: 9999427. DOI: 10.1021/jacs.2c13432.
Schmid L, Chabera P, Ruter I, Prescimone A, Meyer F, Yartsev A Inorg Chem. 2022; 61(40):15853-15863.
PMID: 36167335 PMC: 9554916. DOI: 10.1021/acs.inorgchem.2c01667.
Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas.
Pan J, Li H, Sun K, Tang S, Yu B Molecules. 2022; 27(12).
PMID: 35744775 PMC: 9229220. DOI: 10.3390/molecules27123648.