Suppression of X-ray-induced Dissociation of H2O Molecules in Dense Ice Under Pressure
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We investigated molecular dissociation induced by 10-keV X-ray irradiation in dense ice at pressures up to 40 GPa at 300 K. The dissociation yield estimated from the oxygen K-edge X-ray Raman spectra, showed that the molecular dissociation was enhanced up to 14 GPa and gradually suppressed on further compression to 40 GPa. The molecular dissociation was detected for a rather narrow pressure span of 2-40 GPa by the X-ray spectroscopy. The pressure variation of the dissociation yield was similar to that observed in the electric conductivity of ice VII and likely interpreted in terms of proton mobility.
Hydrogen bond symmetrisation in DO ice observed by neutron diffraction.
Komatsu K, Hattori T, Klotz S, Machida S, Yamashita K, Ito H Nat Commun. 2024; 15(1):5100.
PMID: 38937434 PMC: 11211428. DOI: 10.1038/s41467-024-48932-8.
Komatsu K, Klotz S, Machida S, Sano-Furukawa A, Hattori T, Kagi H Proc Natl Acad Sci U S A. 2020; 117(12):6356-6361.
PMID: 32161135 PMC: 7104228. DOI: 10.1073/pnas.1920447117.