Strong and Reversible Circularly Polarized Luminescence Emission of a Chiral 1,8-Naphthalimide Fluorophore Induced by Excimer Emission and Orderly Aggregation

Overview

Journal Chemistry

Specialty Chemistry

Date 2016 May 4

PMID 27140195

Citations 11

Authors

Yuan Sheng

Jing Ma

Shuai Liu

Yuxiang Wang

Chengjian Zhu

Yixiang Cheng

Affiliations

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Abstract

Four chiral 1,2-diaminocyclohexane (DACH)-based molecules (R,R/S,S-2 and R,R/S,S-4) incorporating 1,8-naphthalimide fluorophores exhibit strong circularly polarized luminescence (CPL) emission signals in common organic solvents. Interestingly, the reversed CPL signals can be observed in the aggregated state, which is due to the orderly aggregation.

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