Complexity of the Relationships Between the Sintering-temperature-dependent Grain Size, Airborne-particle Abrasion, Ageing and Strength of 3Y-TZP Ceramics

Objectives: This study was designed to explore the complex relationships between the sintering-temperature-dependent grain size, airborne-particle abrasion, ageing and strength of 3Y-TZP ceramics.

Methods: Biomedical grade 3Y-TZP powder was used to fabricate 180 discs. Half of them were sintered at 1400°C for 2h and half at 1500°C for 2h. A total of 18 groups of 10 were formed and subjected to the fully crossed experimental protocol of airborne-particle abrasion with Al2O3 at 2.5bar (no abrasion, 50μm, 110μm) and accelerated ageing at 134°C (no ageing, 12h, 48h). The relative amount of monoclinic phase was determined with XRD. The biaxial flexural strength was measured and statistically analyzed using the three-way ANOVA followed by predetermined contrasts and Tukey's HSD test (α=0.05).

Results: The low-temperature-sintered, fine-grained ceramic exhibited an excellent ageing resistance, while the high-temperature-sintered, coarse-grained ceramic experienced a higher surface strengthening and a substantially improved ageing resistance with respect to the airborne-particle abrasion. The overall performance of this material was superior.

Significance: Our results show that the sintering temperature has a minor effect on the flexural strength, but it plays a crucial role in the surface strengthening and the ageing behaviour of 3Y-TZP dental ceramics.