Aspergillus Flavus Conidia-derived Carbon/Sulfur Composite As a Cathode Material for High Performance Lithium-Sulfur Battery
Affiliations
A novel approach was developed to prepare porous carbon materials with an extremely high surface area of 2459.6 m(2)g(-1) by using Aspergillus flavus conidia as precursors. The porous carbon serves as a superior cathode material to anchor sulfur due to its uniform and tortuous morphology, enabling high capacity and good cycle lifetime in lithium sulfur-batteries. Under a current rate of 0.2 C, the carbon-sulfur composites with 56.7 wt% sulfur loading deliver an initial capacity of 1625 mAh g(-1), which is almost equal to the theoretical capacity of sulfur. The good performance may be ascribed to excellent electronic networks constructed by the high-surface-area carbon species. Moreover, the semi-closed architecture of derived carbons can effectively retard the polysulfides dissolution during charge/discharge, resulting in a capacity of 940 mAh g(-1) after 120 charge/discharge cycles.
Li B, Xie M, Yi G, Zhang C RSC Adv. 2022; 10(5):2823-2829.
PMID: 35496086 PMC: 9048591. DOI: 10.1039/c9ra09610h.
A highly efficient double-hierarchical sulfur host for advanced lithium-sulfur batteries.
Hu L, Dai C, Lim J, Chen Y, Lian X, Wang M Chem Sci. 2018; 9(3):666-675.
PMID: 29629134 PMC: 5869551. DOI: 10.1039/c7sc03960c.