Understanding Hydrothermal Transformation from Mn2O3 Particles to Na0.55Mn2O4·1.5H2O Nanosheets, Nanobelts, and Single Crystalline Ultra-long Na4Mn9O18 Nanowires

Overview

Journal Sci Rep

Specialty Science

Date 2015 Dec 16

PMID 26667348

Citations 6

Authors

Yohan Park

Sung Woo Lee

Ki Hyeon Kim

Bong-Ki Min

Arpan Kumar Nayak

Debabrata Pradhan

Youngku Sohn

Affiliations

Soon will be listed here.

Abstract

Manganese oxides are one of the most valuable materials for batteries, fuel cells and catalysis. Herein, we report the change in morphology and phase of as-synthesized Mn2O3 by inserting Na(+) ions. In particular, Mn2O3 nanoparticles were first transformed to 2 nm thin Na0.55Mn2O4·1.5H2O nanosheets and nanobelts via hydrothermal exfoliation and Na cation intercalation, and finally to sub-mm ultra-long single crystalline Na4Mn9O18 nanowires. This paper reports the morphology and phase-dependent magnetic and catalytic (CO oxidation) properties of the as-synthesized nanostructured Na intercalated Mn-based materials.

Citing Articles

Green Synthesis of Metal Nanoparticles with Borojó () Extracts and Their Application in As Removal in Water Matrix.

Murgueitio Herrera E, Jacome G, Stael C, Arroyo G, Izquierdo A, Debut A Nanomaterials (Basel). 2024; 14(18).

PMID: 39330682 PMC: 11434951. DOI: 10.3390/nano14181526.

Novel application of sodium manganese oxide in removing acidic gases in ambient conditions.

Gupta N, Achary S, Viltres H, Bae J, Kim K Sci Rep. 2023; 13(1):2330.

PMID: 36759698 PMC: 9911640. DOI: 10.1038/s41598-023-29274-9.

Soft template-assisted copper-doped sodium dititanate nanosheet/graphene oxide heterostructure for photoreduction of carbon dioxide to liquid fuels.

Lertthanaphol N, Prawiset N, Soontornapaluk P, Kitjanukit N, Neamsung W, Pienutsa N RSC Adv. 2022; 12(37):24362-24373.

PMID: 36128529 PMC: 9415028. DOI: 10.1039/d2ra04283e.

Phyto-inspired and scalable approach for the synthesis of PdO-2MnO: a nano-material for application in water splitting electro-catalysis.

Zahra T, Ahmad K, Thomas A, Zequine C, Gupta R, Malik M RSC Adv. 2022; 10(50):29961-29974.

PMID: 35518230 PMC: 9056303. DOI: 10.1039/d0ra04571c.

Layered Birnessite Cathode with a Displacement/Intercalation Mechanism for High-Performance Aqueous Zinc-Ion Batteries.

Zhai X, Qu J, Hao S, Jing Y, Chang W, Wang J Nanomicro Lett. 2021; 12(1):56.

PMID: 34138296 PMC: 7770783. DOI: 10.1007/s40820-020-0397-3.

References

Khilari S, Pandit S, Das D, Pradhan D . Manganese cobaltite/polypyrrole nanocomposite-based air-cathode for sustainable power generation in the single-chambered microbial fuel cells. Biosens Bioelectron. 2013; 54:534-40. DOI: 10.1016/j.bios.2013.11.044. View

Santhanagopalan S, Balram A, Meng D . Scalable high-power redox capacitors with aligned nanoforests of crystalline MnO₂ nanorods by high voltage electrophoretic deposition. ACS Nano. 2013; 7(3):2114-25. DOI: 10.1021/nn3044462. View

Yabuuchi N, Kubota K, Dahbi M, Komaba S . Research development on sodium-ion batteries. Chem Rev. 2014; 114(23):11636-82. DOI: 10.1021/cr500192f. View

Wang Y, Wang Y, Jia D, Peng Z, Xia Y, Zheng G . All-nanowire based Li-ion full cells using homologous Mn2O3 and LiMn2O4. Nano Lett. 2014; 14(2):1080-4. DOI: 10.1021/nl4047834. View

Mai L, Tian X, Xu X, Chang L, Xu L . Nanowire electrodes for electrochemical energy storage devices. Chem Rev. 2014; 114(23):11828-62. DOI: 10.1021/cr500177a. View

Ning X, Wang Z, Zhang Z . Fermi level shifting, charge transfer and induced magnetic coupling at La0.7Ca0.3MnO3/LaNiO3 interface. Sci Rep. 2015; 5:8460. PMC: 4327574. DOI: 10.1038/srep08460. View

Javed Q, Wang F, Rafique M, Toufiq A, Li Q, Mahmood H . Diameter-controlled synthesis of α-Mn2O3 nanorods and nanowires with enhanced surface morphology and optical properties. Nanotechnology. 2012; 23(41):415603. DOI: 10.1088/0957-4484/23/41/415603. View

Liu Z, Xu K, Sun H, Yin S . One-Step Synthesis of Single-Layer MnO2 Nanosheets with Multi-Role Sodium Dodecyl Sulfate for High-Performance Pseudocapacitors. Small. 2015; 11(18):2182-91. DOI: 10.1002/smll.201402222. View

Chu Q, Wang X, Li Q, Liu X . The tunnel manganese oxide Na4.32Mn9O18: a new Na+ site discovered by single-crystal X-ray diffraction. Acta Crystallogr C. 2011; 67(Pt 2):i10-2. DOI: 10.1107/S0108270110052856. View

10.

Wang H, Xiao F, Yu L, Liu B, Lou X . Hierarchical α-MnO2 nanowires@Ni1-x Mnx Oy nanoflakes core-shell nanostructures for supercapacitors. Small. 2014; 10(15):3181-6. DOI: 10.1002/smll.201303836. View

11.

Lee D, Xu J, Meng Y . An advanced cathode for Na-ion batteries with high rate and excellent structural stability. Phys Chem Chem Phys. 2013; 15(9):3304-12. DOI: 10.1039/c2cp44467d. View

12.

Sauvage F, Laffont L, Tarascon J, Baudrin E . Study of the insertion/deinsertion mechanism of sodium into Na0.44MnO2. Inorg Chem. 2007; 46(8):3289-94. DOI: 10.1021/ic0700250. View

13.

Cao Y, Xiao L, Sushko M, Wang W, Schwenzer B, Xiao J . Sodium ion insertion in hollow carbon nanowires for battery applications. Nano Lett. 2012; 12(7):3783-7. DOI: 10.1021/nl3016957. View

14.

Cao Y, Xiao L, Wang W, Choi D, Nie Z, Yu J . Reversible sodium ion insertion in single crystalline manganese oxide nanowires with long cycle life. Adv Mater. 2011; 23(28):3155-60. DOI: 10.1002/adma.201100904. View

15.

Lee H, Muralidharan P, Ruffo R, Mari C, Cui Y, Kim D . Ultrathin spinel LiMn2O4 nanowires as high power cathode materials for Li-ion batteries. Nano Lett. 2010; 10(10):3852-6. DOI: 10.1021/nl101047f. View

16.

Wang Y, Liu J, Lee B, Qiao R, Yang Z, Xu S . Ti-substituted tunnel-type Na₀.₄₄MnO₂ oxide as a negative electrode for aqueous sodium-ion batteries. Nat Commun. 2015; 6:6401. DOI: 10.1038/ncomms7401. View

17.

Wu Z, Ren W, Wang D, Li F, Liu B, Cheng H . High-energy MnO2 nanowire/graphene and graphene asymmetric electrochemical capacitors. ACS Nano. 2010; 4(10):5835-42. DOI: 10.1021/nn101754k. View

18.

Huang M, Zhang Y, Li F, Zhang L, Ruoff R, Wen Z . Self-assembly of mesoporous nanotubes assembled from interwoven ultrathin birnessite-type MnO2 nanosheets for asymmetric supercapacitors. Sci Rep. 2014; 4:3878. PMC: 3902441. DOI: 10.1038/srep03878. View

19.

Wang F, Dai H, Deng J, Bai G, Ji K, Liu Y . Manganese oxides with rod-, wire-, tube-, and flower-like morphologies: highly effective catalysts for the removal of toluene. Environ Sci Technol. 2012; 46(7):4034-41. DOI: 10.1021/es204038j. View

20.

Lee M, Lee S, Oh P, Kim Y, Cho J . High performance LiMn2O4 cathode materials grown with epitaxial layered nanostructure for Li-ion batteries. Nano Lett. 2014; 14(2):993-9. DOI: 10.1021/nl404430e. View