Gallium(III)corrole-BODIPY Hybrid: Novel Photophysical Properties and First Observation of B-F∙∙∙F Interactions

Overview

Journal Dalton Trans

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2015 Nov 19

PMID 26581014

Citations 3

Authors

Biju Basumatary

R V Ramana Reddy

Subhrajyoti Bhandary

Jeyaraman Sankar

Affiliations

Soon will be listed here.

Abstract

Anchoring a BODIPY onto Ga(III)corrole via a meso-β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for a corrole derivative, due to unique packing. Compound 4 hosts the first example of a novel B-F∙∙∙F interaction as well.

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