» Articles » PMID: 26506332

Enhanced Visible Light Photocatalytic Activity of Br-Doped Bismuth Oxide Formate Nanosheets

Overview
Journal Molecules
Publisher MDPI
Specialty Biology
Date 2015 Oct 28
PMID 26506332
Authors
Affiliations
Soon will be listed here.
Abstract

A facile method was developed to enhance the visible light photocatalytic activity of bismuth oxide formate (BiOCOOH) nanosheets via Br-doping. The as-prepared samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, the Brunauer-Emmett-Teller surface area, UV-vis diffuse reflectance spectroscopy, photoluminescence spectra, and N₂ adsorption-desorption isotherms measurement. The Br- ions replaced the COOH- ions in the layers of BiOCOOH, result in a decreased layer distance. The photocatalytic activity of the as-prepared materials was evaluated by removal of NO in qir at ppb level. The results showed that the Br-doped BiOCOOH nanosheets showed enhanced visible light photocatalytic activtiy with a NO removal of 37.8%. The enhanced activity can be ascribed to the increased visible light absorption and the promoted charge separation.

References
1.
Han X, Kuang Q, Jin M, Xie Z, Zheng L . Synthesis of titania nanosheets with a high percentage of exposed (001) facets and related photocatalytic properties. J Am Chem Soc. 2009; 131(9):3152-3. DOI: 10.1021/ja8092373. View

2.
Ai Z, Ho W, Lee S, Zhang L . Efficient photocatalytic removal of NO in indoor air with hierarchical bismuth oxybromide nanoplate microspheres under visible light. Environ Sci Technol. 2009; 43(11):4143-50. DOI: 10.1021/es9004366. View

3.
McLaren A, Valdes-Solis T, Li G, Tsang S . Shape and size effects of ZnO nanocrystals on photocatalytic activity. J Am Chem Soc. 2009; 131(35):12540-1. DOI: 10.1021/ja9052703. View

4.
Amano F, Nogami K, Tanaka M, Ohtani B . Correlation between surface area and photocatalytic activity for acetaldehyde decomposition over bismuth tungstate particles with a hierarchical structure. Langmuir. 2010; 26(10):7174-80. DOI: 10.1021/la904274c. View

5.
Huo Y, Miao M, Zhang Y, Zhu J, Li H . Aerosol-spraying preparation of a mesoporous hollow spherical BiFeO3 visible photocatalyst with enhanced activity and durability. Chem Commun (Camb). 2010; 47(7):2089-91. DOI: 10.1039/c0cc04247a. View