A Gallium-Substituted Distibene and an Antimony-Analogue Bicyclo[1.1.0]butane: Synthesis and Solid-State Structures

Overview

Journal Angew Chem Int Ed Engl

Specialty Chemistry

Date 2015 Aug 8

PMID 26248643

Citations 15

Authors

Lars Tuscher

Chelladurai Ganesamoorthy

Dieter Blaser

Christoph Wolper

Stephan Schulz

Affiliations

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Abstract

RGa {R=HC[C(Me)N(2,6-iPr2C6H3)]2} reacts with Sb(NMe2)3 with insertion into the Sb-N bond and elimination of RGa(NMe2)2 (2), yielding the Ga-substituted distibene R(Me2N)GaSb=SbGa(NMe2 )R (1). Thermolysis of 1 proceeded with elimination of RGa and 2 and subsequent formation of the bicyclo[1.1.0]butane analogue [R(Me2N)Ga]2Sb4 (3).

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