A New Designed Hydrazine Group-containing Ruthenium Complex Used for Catalytic Hydrogenation of Esters
Overview
Affiliations
A hydrazine group-containing nitrogen-phosphine ligand and corresponding ruthenium complexes were synthesized. When these complexes were used for hydrogenation of esters, excellent performance was observed (TON up to 17, 200). A wide substrate scope was suitable for this catalytic system.
Head M, Joseph B, Keith J, Chianese A Organometallics. 2023; 42(5):347-356.
PMID: 36937786 PMC: 10015984. DOI: 10.1021/acs.organomet.2c00503.
The key role of the latent N-H group in Milstein's catalyst for ester hydrogenation.
Pham J, Jarczyk C, Reynolds E, Kelly S, Kim T, He T Chem Sci. 2022; 12(24):8477-8492.
PMID: 35355805 PMC: 8901127. DOI: 10.1039/d1sc00703c.