A Robust and Efficient Cobalt Molecular Catalyst for CO2 Reduction

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2015 Mar 19

PMID 25783610

Citations 14

Authors

Sharon Lai-Fung Chan

Tsz Lung Lam

Chen Yang

Siu-Cheong Yan

Nga Man Cheng

Affiliations

Soon will be listed here.

Abstract

Visible-light driven CO2 reduction is considered to be a sustainable energy source. However, earth-abundant molecular catalysts with high efficiency and robustness towards solar-driven CO2 reduction are limited. Herein, we report a cobalt complex supported by a tetradentate tripodal ligand, which demonstrates catalytic solar-driven CO2 reduction with TON(CO) > 900 over 70 h in the presence of a photosensitizer.

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