Cold and Controlled Molecular Beams: Production and Applications
Overview
Authors
Affiliations
The field of cold molecules has become an important source of new insight in fundamental chemistry and molecular physics. High-resolution spectroscopy benefits from translationally and internally cold molecules by increased interaction times and reduced spectral congestion. Completely new effects in scattering dynamics become accessible with cold and controlled molecules. Many of these experiments use molecular beams as a starting point for the generation of molecular samples. This review gives an overview of methods to produce beams of cold molecules, starting from supersonic expansions or effusive sources, and provides examples of applications in spectroscopy and molecular dynamics studies.
Theoretical Insights into the Dynamics of Gas-Phase Bimolecular Reactions with Submerged Barriers.
Song H, Guo H ACS Phys Chem Au. 2023; 3(5):406-418.
PMID: 37780541 PMC: 10540288. DOI: 10.1021/acsphyschemau.3c00009.
Reaction of an Ion and a Free Radical near 0 K: He + NO → He + N + O.
Zhelyazkova V, Martins F, Schilling S, Merkt F J Phys Chem A. 2023; 127(6):1458-1468.
PMID: 36752385 PMC: 9940198. DOI: 10.1021/acs.jpca.2c08221.
Xu X, Chen J, Lu X, Fang W, Liu S, Zhang D Chem Sci. 2022; 13(26):7955-7961.
PMID: 35865883 PMC: 9258319. DOI: 10.1039/d2sc01958b.
Zhelyazkova V, Martins F, Agner J, Schmutz H, Merkt F Phys Chem Chem Phys. 2021; 23(38):21606-21622.
PMID: 34569565 PMC: 8494273. DOI: 10.1039/d1cp03116c.
Switch chemistry at cryogenic conditions: quantum tunnelling under electric fields.
Kirshenboim O, Frenklah A, Kozuch S Chem Sci. 2021; 12(9):3179-3187.
PMID: 34164085 PMC: 8179409. DOI: 10.1039/d0sc06295b.