Degeneracy in Cryptophane-xenon Complex Formation in Aqueous Solution

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2014 Dec 18

PMID 25516919

Citations 4

Authors

Sergey Korchak

Wolfgang Kilian

Lorenz Mitschang

Affiliations

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Abstract

The reversible binding of xenon to cryptophane molecules is currently heavily explored for application as a reporter system in NMR. Herein, for aqueous solution, first evidence of degenerate exchange in this host-guest system is presented based on a novel approach using hyperpolarized (129)Xe.

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