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Detection and Monitoring of Toxic Chemical at Ultra Trace Level by Utilizing Doped Nanomaterial

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Journal PLoS One
Date 2014 Oct 21
PMID 25329666
Citations 1
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Abstract

Composite nanoparticles were synthesized by eco-friendly hydrothermal process and characterized by different spectroscopic techniques. All the spectroscopic techniques suggested the synthesis of well crystalline optically active composite nanoparticles with average diameter of ∼ 30 nm. The synthesized nanoparticles were applied for the development of chemical sensor which was fabricated by coating the nanoparticles on silver electrode for the recognition of phthalimide using simple I-V technique. The developed sensor exhibited high sensitivity (1.7361 µA.mM(-1).cm(-2)), lower detection limit (8.0 µM) and long range of detection (77.0 µM to 0.38 M). Further the resistances of composite nanoparticles based sensor was found to be 2.7 MΩ which change from 2.7 to 1.7 with change in phthalimide concentration. The major advantages of the designed sensor over existing sensors are its simple technique, low cost, lower detection limit, high sensitivity and long range of detection. It can detect phthalimide even at trace level and sense over wide range of concentrations. Therefore the composite nanoparticals would be a better choice for the fabrication of phthalimide chemical sensor and would be time and cost substituted implement for environmental safety.

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References
1.
Ansari S, Ansari Z, Wahab R, Kim Y, Khang G, Shin H . Glucose sensor based on nano-baskets of tin oxide templated in porous alumina by plasma enhanced CVD. Biosens Bioelectron. 2008; 23(12):1838-42. DOI: 10.1016/j.bios.2008.02.022. View

2.
Potyrailo R, Mirsky V . Combinatorial and high-throughput development of sensing materials: the first 10 years. Chem Rev. 2008; 108(2):770-813. DOI: 10.1021/cr068127f. View

3.
Khan S, Chani M, Karimov K, Asiri A, Bashir M, Tariq R . Humidity and temperature sensing properties of copper oxide-Si-adhesive nanocomposite. Talanta. 2014; 120:443-9. DOI: 10.1016/j.talanta.2013.11.089. View

4.
Dadashi-Silab S, Tasdelen M, Mohamed Asiri A, Khan S, Yagci Y . Photoinduced atom transfer radical polymerization using semiconductor nanoparticles. Macromol Rapid Commun. 2013; 35(4):454-9. DOI: 10.1002/marc.201300704. View

5.
Ackermann H, Faust H, Kagan Y, Voronina V . Metabolic and toxic behaviours of phthalimide derivatives in albino rat II. Placental passage of chloromethyl phthalimide, oxymethyl phthalimide and phthalimide--their fetal metabolism. Arch Toxicol. 1978; 40(4):255-61. DOI: 10.1007/BF00310330. View