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Cleavage of C-C and C-Si σ-bonds and Their Intramolecular Exchange

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Journal J Am Chem Soc
Specialty Chemistry
Date 2014 Apr 12
PMID 24720573
Citations 14
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Abstract

C-C and C-Si σ-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner.

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