[4+2+2] Cycloaddition Catalyzed by a New Cationic Rhodium-bisphosphine Monooxide Complex

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2014 Apr 8

PMID 24706156

Citations 5

Authors

Gino Martin R Canlas

Scott R Gilbertson

Affiliations

Soon will be listed here.

Abstract

A rhodium-BozPHOS based complex is reported. This complex is competent in catalyzing the [4+2+2] cycloisomerization of cyclooctatrienes in moderate to good yields. The X-ray crystal structure of this complex is reported, along with formation of both bicyclic and tricyclic cyclooctatrienes.

Citing Articles

Cu-catalyzed carboboration of acetylene with Michael acceptors.

Cheng T, Liu B, Wu R, Zhu S Chem Sci. 2022; 13(25):7604-7609.

PMID: 35872813 PMC: 9241969. DOI: 10.1039/d2sc02306g.

Acetylene in Organic Synthesis: Recent Progress and New Uses.

Voronin V, Ledovskaya M, Bogachenkov A, Rodygin K, Ananikov V Molecules. 2018; 23(10).

PMID: 30250005 PMC: 6222752. DOI: 10.3390/molecules23102442.

A thiocyanopalladation/carbocyclization transformation identified through enzymatic screening: stereocontrolled tandem C-SCN and C-C bond formation.

Malik G, Swyka R, Tiwari V, Fei X, Applegate G, Berkowitz D Chem Sci. 2018; 8(12):8050-8060.

PMID: 29568453 PMC: 5855125. DOI: 10.1039/c7sc04083k.

A rational pre-catalyst design for bis-phosphine mono-oxide palladium catalyzed reactions.

Ji Y, Li H, Hyde A, Chen Q, Belyk K, Lexa K Chem Sci. 2017; 8(4):2841-2851.

PMID: 28553522 PMC: 5427683. DOI: 10.1039/c6sc05472b.

Selective Synthesis of Cyclooctanoids by Radical Cyclization of Seven-Membered Lactones: Neutron Diffraction Study of the Stereoselective Deuteration of a Chiral Organosamarium Intermediate.

Just-Baringo X, Clark J, Gutmann M, Procter D Angew Chem Int Ed Engl. 2016; 55(40):12499-502.

PMID: 27600354 PMC: 5113801. DOI: 10.1002/anie.201606792.