Recyclable Polystyrene-supported Siloxane-transfer Agent for Palladium-catalyzed Cross-coupling Reactions

Overview

Journal Org Lett

Publisher American Chemical Society

Specialties Biochemistry
Chemistry

Date 2014 Mar 26

PMID 24661113

Citations 6

Authors

Minh H Nguyen

Amos B Smith 3rd

Affiliations

Soon will be listed here.

Abstract

The rational design, synthesis, and validation of a significantly improved insoluble polymer-supported siloxane-transfer agent has been achieved that permits efficient palladium-catalyzed cross-coupling reactions. The cross-linked polystyrene support facilitates product purification with excellent siloxane recycling. Drawbacks of a previous polymer-supported siloxane-transfer agent, relating to reaction efficiency and polymer stability after repeated cycles, have been addressed.

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