A Bidentate Boryl Ligand: Syntheses of Platinum and Iridium Complexes

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2014 Jan 30

PMID 24473631

Citations 3

Authors

H Schubert

W Leis

H A Mayer

L Wesemann

Affiliations

Soon will be listed here.

Abstract

A methylenediphenylphosphine substituted diazaborole was obtained in a two-step procedure in amounts around 4 g. This B-P ligand was coordinated at platinum and iridium and the structures of the boryl complexes are discussed. In the case of the iridium derivative an interesting boron-boron contact was found.

Citing Articles

Synthesis, Reactivity and Coordination Chemistry of Group 9 PBP Boryl Pincer Complexes: [(PBP)M(PMe)] (M = Co, Rh, Ir; = 1, 2).

Rutz P, Grunenberg J, Kleeberg C Molecules. 2023; 28(17).

PMID: 37687020 PMC: 10488511. DOI: 10.3390/molecules28176191.

Exploring unsymmetrical diboranes(4) as boryl ligand precursors: platinum(ii) bis-boryl complexes.

Drescher Nee Oschmann W, Borner C, Tindall D, Kleeberg C RSC Adv. 2022; 9(7):3900-3911.

PMID: 35518102 PMC: 9060489. DOI: 10.1039/c9ra00170k.

NNB-Type Tridentate Boryl Ligands Enabling a Highly Active Iridium Catalyst for C⁻H Borylation.

Ding S, Wang L, Miao Z, Li P Molecules. 2019; 24(7).

PMID: 30979032 PMC: 6479588. DOI: 10.3390/molecules24071434.